Structure of Cellulose Nanofibril Gels with Alcohols
Our group has been working partially oxidized cellulose nanofibrils which form gels in aqueous formulations. Recently we have observed that these fibrils also gel when dialysed into ethanol, methanol or propanol from aqueous suspensions, but not if directly dispersed in the alcohol from freeze-dried fibrils. This suggests that residual water in the suspensions plays an important role in stabilizing the gels. When NaCl is added the gels become more rigid but also brittle. Addition of sodium dodecylsulphate (SDS) results in stronger gels even though this surfactant does not normally form micelles in alcohols. In this experiment we wish to use contrast variation to determine whether the water is localized near the cellulose nanofibrils, the location of SDS and the effect of added salt on the apparent fibril dimensions and gel structure.
- 10
- 100
- 100 d EtOH d1 d6 Ox...
- 100 d EtOH d1 d6 SD...
- 100 d MeOH d1 d4 Ox...
- 100 d MeOH d1 d4 SD...
- 100 d MeOH h SDS 80...
- 100 d MeOH h SDS 80...
- 100 d MeOH oxcell
- 100 dEtOH d1 d6 Oxcell
- 100 h EtOH Oxcell
- 100 h EtOH SDS Oxce...
- 100 h EtOH SDS Oxce...
- 100 h EtOH dSDS oxc...
- 100 h EtOH dSDS oxc...
- 100 h MeOH D2O _SANS
- 100 h MeOH D2O _TRANS
- 100 h MeOH Oxcell
- 100 h MeOH SDS Oxce...
- 100 h MeOH SDS Oxce...
- 100 h MeOH d SDS ox...
- 100 h MeOH d SDS ox...
- 101
- 102
- 103
- 104
- 106
- 107
- 108
- 109
- 10R
- 10b
- 10i_SANS
- 10i_TRANS
- 11
- 110
- 111
- 112
- 113
- 114
- 115
- 116
- 117
- 118
- 119
- 11b_SANS
- 11b_TRANS
- 12
- 120
- 121
- 127
- 12b_SANS
- 12b_TRANS
- 12i_SANS
- 12i_TRANS
- 13
- 1310297
- 134
- 136
- 13b_SANS
- 13b_TRANS
- 14
- 143
- 14b_SANS
- 14b_TRANS
- 15
- 15b_SANS
- 15b_TRANS
- 16
- 16b_SANS
- 16b_TRANS
- 17
- 17b_SANS
- 17b_TRANS
- 18
- 18b_SANS
- 18b_TRANS
- 19
- 19b_SANS
- 19b_TRANS
- 1Ai_SANS
- 1Ai_TRANS
- 1Bi_SANS
- 1Bi_TRANS
- 1b
- 20
- 20 d EtOH d1 d6 SDS...
- 20 d EtOH d1 d6 no
- 20 d MeOH d1 d4 SDS...
- 20 d MeOH d1 d4 no
- 20 d MeOH d1 d6 h S...
- 20 h EtOH D2O _SANS
- 20 h EtOH D2O _TRANS
- 20 h EtOH d SDS oxc...
- 20 h EtOH d SDS oxc...
- 20 h EtOH no
- 20 h MeOH d SDS oxc...
- 20 h MeOH d SDS oxc...
- 20 h MeOH no
- 20 hMeOH D2O _SANS
- 20 hMeOH D2O _TRANS
- 20b_SANS
- 20b_TRANS
- 21
- 22
- 23
- 24
- 25
- 26
- 27
- 28
- 28r
- 29
- 29r
- 2Bi_SANS
- 2Bi_TRANS
- 2b
- 30
- 31
- 32
- 33
- 34
- 35
- 36
- 37
- 37R
- 38
- 38R
- 39
- 3b
- 40
- 40 d EtOH d1 d6 Oxcell
- 40 d EtOH d1 d6 SDS...
- 40 d EtOH d1 d6 h S...
- 40 d MeOH d1 d4 SDS...
- 40 d MeOH d1 d4 h S...
- 40 d MeOH oxcell
- 40 h EtOH D2O _SANS
- 40 h EtOH D2O _TRANS
- 40 h EtOH d SDS oxc...
- 40 h EtOH d SDS oxc...
- 40 h MeOH D2O _SANS
- 40 h MeOH D2O _TRANS
- 40 h MeOH d SDS oxc...
- 40 h MeOH d SDS oxc...
- 40r
- 41
- 42
- 42r
- 43
- 44
- 45
- 46
- 47
- 48
- 49
- 4Ai_SANS
- 4Ai_TRANS
- 4Bi_SANS
- 4Bi_TRANS
- 4R
- 4b
- 50
- 51 100 d MeOH d1 d4...
- 52
- 53
- 54
- 55
- 56
- 57
- 58
- 58r
- 59
- 5Bi_SANS
- 5Bi_TRANS
- 5R
- 5b
- 60
- 60 d EtOH d1 d6 SDS...
- 60 d EtOH h SDS NaC...
- 60 d MeOH d1 d4 SDS...
- 60 d MeOH d1 d4 h S...
- 60 d MeOH h SDS 80m...
- 60 h EtOH D2O _SANS
- 60 h EtOH D2O _TRANS
- 60 h EtOH Oxcell
- 60 h EtOH d SDS NaC...
- 60 h EtOH d SDS oxc...
- 60 h EtOH d SDS oxc...
- 60 h MeOH D2O _SANS
- 60 h MeOH D2O _TRANS
- 60 h MeOH Oxcell
- 60 h MeOH d SDS 40m...
- 60 h MeOH d SDS oxc...
- 60 h MeOH d SDS oxc...
- 61
- 62
- 63
- 64
- 65
- 65r
- 66
- 67
- 68
- 69
- 6b
- 70
- 71
- 72
- 73
- 74
- 75
- 76
- 79
- 7b
- 80
- 80 d EtOH d1 d6 SDS...
- 80 d EtOH h SDS NaC...
- 80 d MeOH d1 d4 SDS...
- 80 d MeOH h SDS 80m...
- 80 h EeOH d SDS oxc...
- 80 h EtOH D2O _SANS
- 80 h EtOH D2O _TRANS
- 80 h EtOH d SDS
- 80 h MeOH D2O _SANS
- 80 h MeOH D2O _TRANS
- 80 h MeOH SDS Oxcell
- 80 h MeOH d SDS oxc...
- 80 h MeOH d SDS oxc...
- 80mM
- 81
- 81s
- 82
- 82s
- 83
- 84
- 85
- 86
- 87
- 88
- 89
- 8b
- 90
- 91 40 d MeOH oxcell
- 92
- 9380
- 94
- 95
- 96
- 97
- 98
- 99
- 9b
- Ai_SANS
- Ai_TRANS
- Alcohols
- Bi_SANS
- Bi_TRANS
- C12D25OSONa
- C12H25OSO3Na
- C2D5OD
- C2H5OH
- C3D7OD
- C3H7OH
- C6H10O5 n
- CD3OH
- CH3OH
- Celebi
- Cellulose
- Ci_SANS
- Ci_TRANS
- D20 NoSDS_SANS
- D20 NoSDS_TRANS
- D2O
- D2O NaCL no
- D2O NaCl no
- D2O No
- D2O _SANS
- D2O _TRANS
- D2O no
- D2O_SANS
- D2O_TRANS
- Edler
- Gels
- H2O
- H2O _SANS
- H2O _TRANS
- H2O no
- H2O_SANS
- H2O_TRANS
- Jin
- LOQ
- NaCl
- NaCl_SANS
- NaCl_TRANS
- Nanofibril
- No
- Oxcell
- SDS
- SDS NaCl _SANS
- SDS NaCl _TRANS
- SDS NaCl_SANS
- SDS NaCl_TRANS
- SDS Oxcell
- SDS _SANS
- SDS _TRANS
- SDS_SANS
- SDS_TRANS
- Structure
- TK49_TRANS
- TK49can_TRANS
- alcohol _SANS
- alcohol _TRANS
- alcohol d SDS NaCl ...
- alcohol d SDS Oxcell
- b1
- b2
- beam2_TRANS
- beam_TRANS
- cellulose
- cellulose H2O_SANS
- cellulose H2O_TRANS
- cellulose in
- cellulose inD2O_SANS
- cellulose inD2O_TRANS
- d EtOH d1 d6 Oxcell
- d EtOH d1 d6 h SDS ...
- d EtOH d1 d6 h SDS ...
- d MeOH
- d MeOH Oxcell
- d MeOH d1 d4 h SDS ...
- d MeOH d1 d4 h SDS ...
- d MeOH d1 d4 h SDS ...
- d SDS
- d SDS NaCl oxcell
- d SDS NaCl oxcell H...
- d SDS NaCl oxcell H...
- d SDS Oxcell
- d1 d4 Oxcell
- d1 d4 h SDS NaCl Ox...
- d2O_SANS
- d2O_TRANS
- d4
- d6ethanol
- d8propanol
- dEtOH d1 d6 h SDS 4...
- dEtOH_SANS
- dEtOH_TRANS
- dMeOH_SANS
- dMeOH_TRANS
- direct
- empty
- h EtOH Oxcell
- h EtOH d SDS 40mM N...
- h EtOH d SDS 80mM N...
- h EtOH d SDS 80mM O...
- h EtOH d SDS NaCl O...
- h EtOH d SDS no
- h MeOH Oxcell
- h MeOH Oxcellin
- h MeOH d SDS 80mM N...
- h MeOH d SDS 80mM O...
- h MeOH d SDS NaCL O...
- h MeOH d SDS NaCl O...
- h MeOH d SDS Oxcell
- h MeOH d SDS no
- h MeOH dSDS no
- h SDS
- h4
- h6ethanol
- h8propanol
- hEtOH _SANS
- hEtOH _TRANS
- hEtOH_SANS
- hEtOH_TRANS
- hMeOH_SANS
- hMeOH_TRANS
- methanol
- nanofibrils
- no
- only_SANS
- only_TRANS
- oxcell
- oxidised
- partially
- rerun_SANS
- rerun_TRANS
- tk49_SANS
- tk49_TRANS
- tk49can_SANS
- tk49can_TRANS
Provenance | |
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Creator | Professor Karen Edler; Ms Duygu Celebi; Mr Yun Jin; Dr Gavin Hazell; Dr Ilaria Idini; Dr Amani El Fagui |
Publisher | ISIS Neutron and Muon Source |
Publication Year | 2016 |
Rights | CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/ |
OpenAccess | true |
Contact | isisdata(at)stfc.ac.uk |
Representation | |
---|---|
Resource Type | Dataset |
Discipline | Photon- and Neutron Geosciences |
Temporal Coverage Begin | 2013-05-27T07:58:03Z |
Temporal Coverage End | 2013-06-03T08:09:07Z |