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Methanol based elongation of propionate and propionate and acetate in continu...
Continuous methanol based chain elongation of propionate to n-valerate was performed in a mixed culture reactor. Additionally, the study shows simultaneous methanol based... -
Meso- and micro-structure of protic ionic liquid / methanol mixtures
Protic ionic liquids (PILs) are an interesting sub-class of room temperature ionic liquids. They differ from conventional, a protic ionic liquids, because of the major role... -
Morphology-activity relationships in catalysis promoted by MoOx nanoparticles
Metal and metal oxide nanostructures can be prepared in much different morphology (nanowires, nanobelts, nanofibres etc.) which are known to exhibit better adjustable properties... -
INS Determination of the Surface Properties of Nanoparticle Pollutants
Metal oxide nanoparticles are a form of pollution generated by a number of industrial procedures, and there is evidence that this class of nanoparticle can have a detrimental... -
Insulator to metal transition in TiOCl at high pressures
We propose to study the high temperature structure of TiOCl where a pressure induced metal to insulator transition has been reported recently by Kuntscher et al.Due to our... -
Probing Ligand Flexibility using Quasielastic Neutron Scattering
Transition metal catalysts are ubiquitous in the academic and industrial study and application of synthetic chemistry. The properties of these catalysts can be augmented by... -
Crystal structures of methanol mono-ammoniate (CD3OD.ND3) and methanol hemi-a...
Mixtures of methanol with water and ammonia dominate the chemistry of cometary bodies, leftovers of the building blocks of the outer planets. We have previously determined the... -
The Location of Guests in Metal-Organic Frameworks Using IINS
Metal-organic framework materials are a topical family of nanoporous solids that have potential applications in molecular storage, separation and catalysis. This includes the... -
The application of INS to examine high specification Fe Fischer-Tropsch catal...
Over the last 4-5 years the research team have been developing INS methodology that can be applied to investigate Fe Fischer-Tropsch (F-T) catalysts. The first stage of that... -
Comparison of the Compression Behaviour of BaSnO3 and Ba0.575Sr0.425SnO3
We propose to study the effect of pressure on the structure of the tetragonal Ba0.575Sr0.425SnO3, The behaviour will be compared to the compression of the cubic BaSnO3 (parent... -
Observation of intermediates on a transfer hydrogenation catalyst
The design and development of novel catalysts for chemical synthesis is incredibly important from both academic and industrial perspectives. Approximately 90 % of all commercial... -
calcite oil interface
The interface of CaCO3 (calcite) and oil is of paramount importance in a number of key academic and industrial areas, not least oil recovery. Neutron reflection has proved to be... -
Thermal expansion and simultaneous Raman spectroscopy of methanol ammoniates,...
We have recently determined the structures of methanol-monoammoniate, and Me-hemiammoniate from neutron powder data. These are found to have different degrees of C-H...O... -
Using small angle neutron diffraction to describe the status of water in solu...
Fish oocytes and embryos are complex cryobiological objects for which, successful cryopreservation has still not been achieved. This circumstance seriously restricts the... -
The application of INS to investigate the active phase of methane steam refor...
A previous allocation of beamtime on MAPS [RB720354] revealed the vibrational fingerprint of methane reforming catalysts operating under so-called ¿dry¿ reforming conditions.... -
INS studies of the interaction of propene with ZSM-5
Fluidised Catalytic Cracking (FCC) units are one of the major conversion units in modern petrochemical refineries. ZSM-5 additives are used in FCC units to convert gasoline... -
Microscopic structure of acetic acid in water and methanol
Some of the most important chemical reactions involve Brønsted acids and bases where the solvation structure and transport dynamics of charged defects in hydrogen-bonded... -
Higher resolution inspection of the hydrocarbon pool connected with the metha...
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously via... -
INS Study of Cu-based methanol synthesis catalysts
In low-pressure methanol synthesis from fossil synthesis gas, Cu/ZnO/Al2O3-catalysts are successfully used in industrial synthesis at 250°C and 50-100 bar, but the exact... -
Structure of Cellulose Nanofibril Gels with Alcohols
Our group has been working partially oxidized cellulose nanofibrils which form gels in aqueous formulations. Recently we have observed that these fibrils also gel when dialysed...
