Structure and interactions in model and real anti-reflective coatings

DOI

This proposal seeks to exploit contrast variation SANS to study a multi-component system, spanning a wide range of colloidal length scales. The multi-component system under question is a model antireflective (AR) coating formulation, comprised of silica-polymer core-shell nanocomposites. To be clear, these are core-shell nanocomposites with silica shells (5- 10 nm) and a polymer latex cores (~ 60 nm diameter, cryo-TEM and DLS). Core-shell nanocomposites are grown by addition of a silicon alkoxide to methacrylate-based polymer latex in the presence of a background equilibrium cationic co-polymer (Co-Pol), which is always present in this process and critically acts as the site of silication for core-shell particles. The proposal centres around a contrast-match study of the copolymer with the polymer latex and core-shell particles in turn, to probe interactions.

Identifier
DOI https://doi.org/10.5286/ISIS.E.79107920
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/79107920
Provenance
Creator Professor Julian Eastoe; Miss Jocelyn Peach; Dr Sarah Rogers; Mr Jonny Pegg; Dr Gavin Hazell; Mr Miguel Hinojosa Navarro; Dr Adam Czajka
Publisher ISIS Neutron and Muon Source
Publication Year 2019
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2016-04-16T08:00:00Z
Temporal Coverage End 2016-04-18T08:00:00Z