Adsorbtion from nematic mixtures

DOI

The aim is to measure the preferential adsorption of one component in a nematic mixture. The base is 4-pentyl 4¿- cyanobiphenyl (5CB) and it is doped with 4-pentyl 4¿- cyanoterphenyl (5CT). The aim of this proposal is to measure the adsorption of 5CT at interfaces between a 5CB/5CT mixture and solid alignment layers. Temperature and concentration will be varied to determine the free energy and enthalpy of adsorption. Preliminary data has indicated adsorption can be detected by neutron reflection, confirming feasibility of the proposed measurements. A long term aim is to investigate the effect of liquid crystals in confinement, between two interfaces with conflicting alignment properties. We therefore wish to make the 5CT absorption measurements using three types of alignment layer with different director anchoring properties.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24087868
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24087868
Provenance
Creator Professor Rob Richardson; Dr Laura Mears; Professor Terence Cosgrove; Dr Wiebe De Vos; Dr Stuart Prescott; Dr Anne Prescott; Dr Herbert Zimmermann
Publisher ISIS Neutron and Muon Source
Publication Year 2014
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2011-10-07T07:27:24Z
Temporal Coverage End 2011-12-22T14:58:52Z