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Distribution of End-Functionalized Polymers in Semi-Crystalline Blends
Although the surface properties and self-organisation of end-functional polymers in amorphous blends are well understood, the influence of crystallinity has received little... -
Interfacial Adsorbtion from Nematic Mixtures
The aim is to determine the amount of absorbtion of the one component of a mixture at the nemtic/air interface using neutron reflection. The host material in the mixture will be... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Adsorbtion from nematic mixtures
The aim is to measure the preferential adsorption of one component in a nematic mixture. The base is 4-pentyl 4¿- cyanobiphenyl (5CB) and it is doped with 4-pentyl 4¿-... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
Multiscale time resolving study of the crystallisation of nanofibrils of a mo...
This experiment exploits the unique capability of Nimrod to study the crystallisation of nanofibrils of a molecular gelator dibenzylidene sorbitol from alkane solutions on... -
Nonfluorous Cosurfactant/Hyperbranched Surfactant Mixtures for W/CO2 Microemu...
This proposal aims to explore cheap and environmental-benign cosurfactants (or cosolvents) for yielding CO2-philic hydrocarbon surfactant/water/CO2 microemulsions (W/CO2... -
Adsorption of an Anionic Surfactant on Anionic Surfaces in the Presence of Ca...
In this proposal we request beamtime on the Inter reflectometer to study the unexpected adsorption behaviour of the surfactant bis(2-ethylhexyl) sulfosuccinate caesium salt... -
Effects of Architecture on Polymer Diffusion
As part of a wider study we are studying the effects of polymer architecture between cyclic and linear polymers. From ATR-FTIR measurements we observe clear differences between... -
Structural development during crystallisation of synthetic polymers
We wish to exploit the unique capability of Nimrod to move forward the long standing issue of the way in which long chain polymers crystallise. There are two key length scales:... -
Probing the Mobility of Simple Phenolic Lignin Monomers for Model Development...
Due to the importance of developing efficient biomass conversion processes, the mobility of lignin constituents phenol and catechol in zeolite Beta will be studied using QENS.... -
Influence of Aliphatic for Tackifiers on Glassy Domains in Hot Melt Adhesives
We have recently shown by neutron reflectometry, that the glassy styrenic blocks, normally assumed to be impervious to aliphatic oligomers do in fact show a significant level of... -
Solvation and structure of lithium in bis{(trifluoromethyl)sulfonyl}imide bas...
The use of ionic liquids for electrochemical devices such as supercapacitors, dye sensitised solar cells and lithium ion batteries has led to significant advances in technology.... -
Evolution of magnetic ordering in three oxide arsenides containing CrO2 layer...
This experiment will probe the evolution of magnetic ordering in compounds with square planar Cr2+ ions in CrO2 oxide layers, and the interaction of these moments with Mn2+ and... -
A Model for Tackifier Elastomer Interaction
Oligomers are commonly added to adhesives in order to improve surface tack properties. However, it is also important that the oligomers do not adversely affect the solid (glassy... -
Dispersed lamellar phases in dense CO2
This proposal aims to explore these dispersed lamellar phases with a variety of F7H4 derivatives,to help understand their formation in supercritical CO2 (sc-CO2). The focus is... -
Practical viscosifiers for supercritical CO2
This proposal explores headgroup-free, fluorocarbon-hydrocarbon hybrid compounds able toform viscous elongated aggregates in supercritical CO2 with the aim of improving... -
Towards the development of carbonitrides as novel two-stage regenerable reage...
We are examining a number of cobalt-molybdenum carbonitrides as possible catalysts for reactions that produce nitrogen-containing organic molecules. There is good evidence that... -
The formation of elongated aggregates in supercritical CO2 through the mixing...
This proposal involves manipulating the curvature of aggregated polar materials in supercritical CO2 (scCO2) by tuning the mixing ratio of fluorocarbon (FC) and hydrocarbon (HC)... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to...