-
The Dynamics of Molecular Hydrogen in Synthetic Na-Laponite
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared Na-laponite clay. There are linked... -
The interpenetration of two poly(ethylene oxide) polymer brushes under confin...
Coating two surfaces with polymer brushes has been shown on many occasions to reduce friction by orders of magnitude. These ultra-low frictions are believed to stem from be the... -
Determination of the bondlength of the surface hydride in PdH
Supported palladium particles are used as catalysts in many processes. In the course of investigation of Pd-based catalysts used for the selective hydrogenation of nitro-arenes... -
Adsorbtion from nematic mixtures
The aim is to measure the preferential adsorption of one component in a nematic mixture. The base is 4-pentyl 4¿- cyanobiphenyl (5CB) and it is doped with 4-pentyl 4¿-... -
Investigating reversible heterolytic H2 activation in Frustrated Lewis Acid B...
Remarkably, hydrogen may be activated for chemical reaction at room temperature using a new family of frustrated Lewis acid-base pair (FLB) materials. In these complexes... -
Solid state hydrogen storage in carbon nitride materials for practical applic...
Existing fossil fuels are on the verge of extinction and thus in this scenario renewable fuels are need of hour. Hydrogen is potential energy source and can be stored in carbon... -
Crystal structures and magnetic order in metal/ammonia intercalates of FeSe
This is a proposal to determine the magnetic structures of the Rb/NH3 and K/NH3 intercalates of FeSe. These compounds exhibit superconductivity when freshly prepared, but... -
Study of gas absorption in MCM41.
We have studied the absorption of nitrogen gas in MCM41 on NIMROD at a pressure of 1 bar and at temperatures to 87K (A K Soper and D T Bowron, Chem. Phys. Lett., DOI:... -
Mechanism of hydrogen residue in metal hydrides formed from high-entropy allo...
High-entropy alloys (HEAs) typically contain four or more principle elements in equimolar amounts. We have recently discovered the first bcc HEA-based hydride with reversible... -
Surface structures of polycations in confined geometries
A second-generation surface force style apparatus has been developed to probe the inter-surface and near-surface structures under compressive forces. Systems of current academic... -
Investigating the Structure of Porous Liquids
Porous liquids are a counter-intuitive new class of porous material consisting of a liquid with permanent, empty holes. They are unique in that they combine the fluidity of... -
The Dynamics of Molecular Hydrogen in Synthetic Clays
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual... -
Microscopic structure of nitric oxide (NO): A comparison between experiments ...
The Nobel Prize in Physiology and Medicine (1998) was awarded for the finding that nitric oxide (NO) is a ubiquitous signalling molecule in the cardiovascular system. Its... -
Sub-Kelvin helium confinement in crystalline nanopores
Under confinement in porous media, helium-4 excitations develop a complicate behaviour and, in addition to a bulk-like spectrum, a second branch emerges due to helium-4 atoms in... -
Kinetics of Molecular Intercalation into Graphite Oxide
The search for new porous materials is increasingly be driven by socio-economic pressure to diversify our energy supply and minimize environmental impact. Carbon-based... -
Nature of guest-host interactions in novel porous carbon materials
The goal of this proposal is to investigate the nature of the guest-host interactions in novel porous carbide-derived carbon (CDC) using TOSCA. The advantage of porous carbons... -
Dynamic Nuclear Polarization in GaAs by electrical spin injection
We propose to measure the dynamic nuclear polarization in a GaAs-based structure caused by electrical injection of a spin-polarized current using polarized neutron... -
Hydrogen diffusion in Palladium-Silver membranes measured by QENS
Hydrogen selective membranes based on palladium are important for technological processes such as isotopic separation and gas purification.In general, a Pd membrane when... -
Investigating the effect of pore structure upon interactions of hydrogen with...
Three MOFs samples with high hydrogen storage capacities at 77K, and high surface area, are willing to be analyzed. In order to investigate hydrogen interactions within the... -
Nuclear quantum effects and ortho-to-para conversion for hydrogen adsorbed in...
Metal-organic frameworks represent one of the most studied options to store hydrogen for clean-energy applications. Nuclear quantum effects, and in particular zero-point...