Incorporation of d- or f-block metals into ligand systems that renders a metal complex surface active or drives its partitioning into surfactant phases enables the localisation of chemical functionality at interfaces. In Cardiff we have undertaken an extensive study by small-angle neutron scattering of the micelle and oil in water microemulsion structure of a family of homologous series of surfactants containing various metal ions and their counterions. Here, we wish to broaden this study to water in oil metallomicroemulsions, both hydrocarbon and fluorocarbon containing systems.