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Ionic liquid containing microemulsions
The aim of this experiment is to characterise several novel ionic liquid ¿ oil and ionic liquid ¿ water microemulsions via SANS prior to their use in the synthesis of metallic... -
Controlled Assembly of Cationic Polythiophene-Surfactant Complexes
We intend to study the phase behaviour of 2 cationic polythiophenes, P3MAHT and P3ImiHT, in the presence of the perfluorinated surfactant potassium... -
Conformational behaviour of amphiphilic polymethacrylate-poly(acrylic acid) c...
We shall use SANS to investigate the conformational behaviour of a range of amphiphilic copolymers with varying architectures: graft, hyperbranched block, hyperbranched random,... -
Peptide resistance in asymmetric MRSA-mimetic vesicles
We have been investigating the influcence of the cationic staphylococcal lipid lysyl-phosphatidylglycerol (L-PG) on bacterial resistance to antimicrobial peptides (AMPs). Using... -
Aggregation in ionic liquids
The aim of this experiment is to investigate surfactant aggregation in ionic liquids and also ionic liquid ¿ oil and ionic liquid ¿ water microemulsions via SANS. Contrast... -
Complex evolution of solution microstructure in LAS / nonionic surfactant mix...
This proposal is part of a broad programme of collaborative research between RAL / Oxford and Unilever, using predominantly scattering techniques to investigate the nature of... -
Characterising micelles formed from new polymerizable amphiphiles derived fro...
Amphiphiles derived from amino acids are important functional materials. The amino, carboxyl and side chain groups present in the chemical structure of amino acids provide wide... -
Influence of polymer molecular weight on polymer stabilized lipid nanodiscs
Nanostructured lipid aggregates offer enormous potential as tools for membrane structural biology and biophysics. Poly(Styrene-Maleic Acid) stabilized lipid nanodiscs have a... -
Hydrophobicity ¿ The Key to Polymer-Drug Conjugate Conformation
The use of polymer-drug conjugates for the delivery of drugs to specific sites of disease within the body has shown much clinical promise. It has become clear that the... -
Organogels for applications in CO2
This proposal aims to explore organogel systems, like those recently decsribed1-3, but made from new CO2 philic surfactant-gelators. These have been synthesised to feature... -
Opening up microemulsion phases in CO2
New types of water-in-CO2 microemulsions using mixed surfactant systems will be investigated by high-pressure SANS (HP-SANS). Exciting new results (see report on RB820030) have... -
Formulating polymer solutions to stabilise polymeric foams
Polyurethane foams (PUF) are commonly prepared by mixing Pluronic type copolymers and isocyanate reactive monomers in the presence of additives e.g. catalysts, blowing agents... -
Gold-loaded microgels
Recent results show that gold nanoparticles (Au-NPs) can be included into microgels (MGs). UV-visible spectra (Figure 1) suggest the original Au-NP sols retain their size and... -
Structure of alkylated aza-crown ether inverse micelles
Ion transfer through fluid-fluid interfaces plays decisive roles in many natural and industrial processes. In studies of Cu(II) transport by Permeation Liquid Membrane (PLM)... -
Response of PAN-pyrene-micelle based sensors to metal ions
We have been studying the solution interactions leading to formation of solid polymer-surfactant films at the air-solution interface. We want to use the mesostructures in the... -
Curvature effects in polyelectrolyte-surfactant solution interactions
This proposal continues our investigations into polyelectrolyte-surfactant solutions which form thin films at the air-solution interface. Our previous work has investigated the... -
Study of the interaction of various LPSs with Lactoferrin.
Proposal is focused on the study of the interactions of some lypopolysaccharides (LPSs) with Lactoferrin. LPSs compose about 70-80% of the outer membrane of Gram negative... -
New surfactants forming anisotropic micelles and microemulsions in CO2
An analogue of the popular surfactant AOT with isopropyl glycol tails (IG-AOT, Figure.1) has been recently designed as a co-surfactant for water-in-CO2 (w/c) systems: stable... -
Polystrene chain conformations in good solvents and electrospun fibres
This proposal is centered on the preparation of nanoscale fibres prepared by electrospinning and is the focus of the final year PhD programme of Saeed Mohan. These experiments... -
CO2 foams stabilized by W/CO2 interfacially active hydrocarbon surfactants an...
CO2 foams can be formed in water/carbon dioxide (W/CO2) mixtures with the aid of W/CO2 interfacially active hydrocarbon surfactants and surface treated silica nanoparticles...