-
Structure of Meibomian lpid films at the air-water interface using
The tear film of the eye has an outer meibomian lipid layer (TFLL) that allows tears to spread across the eye and remain stable. Our Langmuir trough and other studies show that... -
Structural phase transitions in proton conducting BaCe0.8Y0.2O3-d as function...
The structure dependence of BaCe0.8Y0.2O3-d (BCY-20), a leading proton conducting material, will be studied as a function of temperature and, critically, controlled atmosphere... -
In-situ neutron diffraction investigation of Ni-based batteries
Ni-based secondary batteries are currently used in many applications, however, the structural changes at the electrodes are not fully characterized and neutron diffraction is a... -
Neutron diffraction of amorphous magnesium carbonate (AMC)
Biominerals, including calcium carbonates, are found in a range of organisms. Although amorphous calcium carbonate (ACC) is inherently unstable, it is a key material in... -
Adsorption kinetics from polymer/surfactant systems; PSS/CnTAB
Polymer-surfactant mixtures are widely used in commercial formulations in personal care, pharmaceutical and agrochemical, cleaning, automotive and food industries. The... -
Determination of the Low Temperature Crystal Structure of Cobalt Adipate
This experiment will use high resolution neutron diffraction to investigate the crystal and magnetic structure of the cobalt adipate framework, Co(CO2(CH2)4CO2), at lower... -
The competition between two polymers for adsorption onto one surface
The behaviour of multiple polymers in competition for colloidal silica has previously been investigated in our group using solvent relaxation nuclear magnetic resonance. We... -
In-situ study of structure-property relationships on proton conducting perovs...
Significant research has been given towards synthesis and characterisation of electrolyte materials with high proton conductivity for intermediate temperature range (200-600°C)... -
Can surfactants be pushed out of polymer layers by applying compression?
For many applications such as paints, foods and drug formulations, aggregation of colloidal particles is prevented by combining polymer and surfactant adsorption. Key to this... -
Pressure Effects on Proton Migration 3,5-pyridinedicarboxylic Acid
Hydrogen bonds are ubiquitous in materials across the chemical spectrum, from inorganic to biological. They influence the structure, the functionality, and therefore the... -
Inelastic Neutron Scattering Experiments in the Sulfur-Ammonia Photothermoche...
The following proposal aims to ellucidate the role of ammonium ions in sulfite oxidation reaction. The key step in the sulfur-ammonia photothermochemical cycle, which is one of... -
W I F David - Energy Project
W I F David - Energy Project -
Neutron diffraction of fully deuterated amorphous calcium phosphate (d-ACP)
Bone growth involves the formation of hydroxyapatite, HA, nanocrystals in the body. In vitro studies showed that HA does not precipitate directly, but that amorphous calcium... -
Measuring phospholipid flip-flop rates across vesicle bilayers
Asymmetry across biological membranes is vital for a wide range of organelle and cellular functions. Significant differences in lipid composition have been found between the... -
Neutron reflectivity study on sefl-repairing polymer brushes by surface segre...
We have recently studied the surface segregations of amphiphilic block copolymers blended in a matrix of cross-linked poly(dimethyl siloxane). In this system, while the... -
An investigation on the adsorption of reverse pluronic and additives on metal...
PPO-PEO-PPO copolymer-based lubricant with extreme pressure or friction modifier additives has been introduced as boundary lubricant in metal forming. The Pluronic reverse... -
Lithium amide: calcium hydride (1:1) as the basis for a new hydrogen storage ...
A definitive structural model of LiCaN from powder neutron diffraction (PND) is an important first step towards a systematic study of the process and mechanism of hydrogenation... -
Telechelic Polymer - Homopolymer Blends
We have recently embarked on a new 1 year project funded by Michelin to explore the self-associatation and mechanical properties of telechelic rubbery materials. Such materials... -
Distribution of comonomer units in biodegradable semicrystalline copolymers
Aliphatic polyesters are the most attractive candidates for biodegradable polymers. To improve their physical properties while maintaining biodegradability, incorporating... -
The solution structure of the OmpF¿Colicin N complex in lipid nanodiscs
We have previously solved the structure by SANS of the complex between the outer membrane protein F of E coi and the toxin colicin N which is a large antibiotic protein. This...
