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Surfactant mixing at hydrophilic solid/liquid interfaces: (A) air/water measu...
The overall objective is to model the amount and composition of adsorbed mixtures of three types of zwitterionic surfactant and two charged surfactants at the silica/water... -
DPPC bilayer oxidation by aqueous singlet oxygen
Oxidation of membrane lipids by Reactive Oxygen Species, ROS, in cells may impact ageing, cell apoptosis and cancer. We propose to use our skills obtained studying the oxidation... -
Relation between surface tension and adsorbed amount of proteins at the air/w...
The surface tension of proteins often exhibits a reproducible lagtime, which is sensitiv to a range of conditions such as concentration, pH, ionic strength. We have also found... -
Neutron Reflection from a Biomineralisation Glycosaminoglycan on Calcite
Here we aim to structurally characterise the formation of adsorbed monolayers of heparin on calcite to address how these species influence biomineralisation and the inhibition... -
Adsorption of liquid crystal nanostructured particles to model hydrophilic an...
Cubosomes and hexosomes are particles with internal liquid crystal structures of the bicontinuous cubic or reverse hexagonal nanostructures respectively. The nanostructure... -
Kinetics of surfactant multilayer formation / dissolution at interfaces
The spontaneous formation of multilayer structures at surfaces and interfaces from self-assembly in mixed surfactant and in polymer / surfactant mixtures are being increasingly... -
Developing a generic gravimetric method to determine the composition of films...
We propose to develop a new and generic, multi-probe technique to characterize the mass, and changes in mass, of material probed in a NR experiment. This methodology will be... -
Polymer-surfactant films containing glucose sensors and structure directing p...
This proposal continues our research on mesostructured surfactant templated polymer films. The films are robust and form spontaneously at the air-water interface. Recent... -
Can surfactants be pushed out of polymer layers by applying compression?
For many applications such as paints, foods and drug formulations, aggregation of colloidal particles is prevented by combining polymer and surfactant adsorption. Key to this... -
Novel block bottlebrush polyelectrolytes: The effect of cationic block charge...
In this work we will study a novel block copolymers consisting of a linear cationic block and uncharged bottle-brush block having 45 units long poly(ethylene oxide) side chains.... -
Structure of Adsorbed Surfactant Layers at the Ethanoalammonium Nitrate¿Air I...
We have recently completed x-ray reflectivity, neutron reflectivity [RB810041], and sum frequency spectroscopy experiments using non-ionic surfactants adsorbed at the... -
Matrix Effects on Polymer Surface Segregation
We have used neutron reflectivity and complementary techniques of ion beam analysis and contact angle to understand the adsorption behaviour of multi-fluoro end functional... -
Surface adsorption in highly non-ideal multi-component surfactant mixtures
This proposal is about the development of sustainable detergency based formulations, based on the blending of biosurfactants with conventional surfactants, and is part of a CASE... -
Antibody-polysorbate surface interactions
Of concern to the bioprocessing industry is the manner in which polysorbates included in solution formulations of antibodies affect the kinetics and equilibrium state of... -
Novel Alginate Adsorption onto High Surface Energy Crystal Faces of Calcite
In this novel proposal we will investigate adsorption onto the non-equilibrium face of calcite the first time this has been attempted. This will compliment and extend our... -
A method to weigh polymer films and adsorbates during neutron reflectivity me...
With the advent of TS-II, there is a drive to probe more complex and multicomponent systems using neutron reflectivity. In such studies, confidence associated with model Nb fits... -
Effect of alkyl chain length on the adsorption of n-alkyl phosphocholine surf...
This proposal relates to the study of adsorption of n-dodecyl phosphocholine (C12PC) at the oil-water interface. The thickness of the adsorbed monolayers measured for dC12hPC... -
Conformation of di-stearoyl-polyethylene glycol surfactants as enhancers of b...
This proposal relates to the structural studies of Di-stearoyl and di-palmitoyl Polyethylene glycol derivates as a function of the PEG head group at the air-water and the... -
Lagtimes in the adsorption of proteins at the air/water interface
Adsorption of proteins at all surfaces has a characteristic lagtime which can be monitored by surface tension at the air/water interface. The cause of the lagtime is not... -
Composition depth profiling of novel spray-coated plastic solar cell materials
We propose to study a range of new lower energy gap organic photovoltaic (OPV) materials deposited by spray coating using neutron reflectivity. The new materials to be studied...