Hydrochemistry of water samples from CTD and towfish during METEOR cruise M147

DOI

The main component of this data base comprises elemental concentrations associated with dissolved organic matter obtained from samples collected on Meteor cruise M147 (May 2018). The data supports the manuscript Trace metal stoichiometry of dissolved organic matter in the Amazon Estuary. Dissolved organic matter (DOM) comprises a distinct component of the Earth's hydrosphere and provides a link between the biogeochemical cycles of carbon, nutrients, and trace metals (TMs). Binding of TMs to DOM is thought to result in a TM pool with DOM-like biogeochemistry. In this manuscript, we determined elemental stoichiometries of aluminium, iron, copper, nickel, zinc, cobalt and manganese associated with a fraction of the DOM pool isolated by solid phase extraction at ambient pH (DOMSPE-amb) from the Amazon estuary. We found the rank order of TM stoichiometry within the DOMSPE-amb fraction was underpinned by the chemical periodicity of the TM. Furthermore, the biogeochemistry of the TMSPE-amb pool was related to the chemical hardness of the TM ion. Thus, the biogeochemistry of TMs bound to the DOMSPE-amb component in the Amazon estuary was determined by the chemical nature of the TM and not by that of the DOMSPE-amb.

0 in the data column means below detection limit

Identifier
DOI https://doi.org/10.1594/PANGAEA.941355
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.941355
Provenance
Creator Gledhill, Martha ORCID logo; Hollister, Adrienne ORCID logo; Siedel, Michael; Zhu, Kechen ORCID logo; Achterberg, Eric Pieter; Dittmar, Thorsten ORCID logo; Koschinsky, Andrea ORCID logo
Publisher PANGAEA
Publication Year 2022
Funding Reference Deutsche Forschungsgemeinschaft, Bonn https://doi.org/10.13039/501100001659 Crossref Funder ID GL807/2-1 https://gepris.dfg.de/gepris/projekt/393829236?language=en Development of a consistent thermodynamic model of trace element - organic matter interactions in the Ocean
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 917 data points
Discipline Earth System Research
Spatial Coverage (-51.086W, -0.645S, -46.449E, 5.120N)
Temporal Coverage Begin 2018-04-30T16:59:30Z
Temporal Coverage End 2018-05-16T08:08:30Z