Dissolved and particulate trace metal and rare earth element (REE) concentrations during a mesocosm based phytoplankton bloom simulating intertidal coastal conditions

DOI

We analyzed concentrations of dissolved and particulate trace metals, including iron (Fe), manganese (Mn), vanadium (V), molybdenum (Mo), thallium (Tl), and rare earth elements (REE), during a mesocosm-based phytoplankton summer bloom mimicking the intertidal zone of the southern North Sea (Jade Bay). The studies aimed to identify key drivers controlling their biogeochemical cycling in dynamic, high-productivity coastal environments. Our results highlight the tidally influenced coastal zone as a critical interface that alters the behavior of supposedly conservative elements such as Mo and Tl (Mori et al., 2021) as well as natural and anthropogenic REE (incl., lanthanum, samarium, and gadolinium) (Mori et al., under review). Trace metal concentrations and shale-normalized REE patterns, determined by quadrupole inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma–optical emission spectrometry (ICP-OES), were combined with biogeochemical bulk parameters and pigment-based assessments of phytoplankton growth and community composition (Mustaffa et al., 2020). Trace metal and REE cycling were evaluated in relation to phytoplankton dynamics, particulate organic matter composition (C, N, P), dissolved organic carbon, total dissolved nitrogen, and macronutrient concentrations (nitrate, ammonium, silicate, and inorganic phosphate). The dataset was obtained during a Planktotron-based mesocosm experiment conducted within the framework of the Coastal Ocean Darkening project (Mustaffa et al., 2020).

Identifier
DOI https://doi.org/10.1594/PANGAEA.990362
Related Identifier References https://doi.org/10.1016/j.marchem.2020.103910
Related Identifier References https://doi.org/10.2139/ssrn.5691052
Related Identifier References https://doi.org/10.3389/fmars.2020.547829
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.990362
Provenance
Creator Mori, Corinna ORCID logo; Striebel, Maren ORCID logo; Brumsack, Hans-Jürgen ORCID logo; Dittmar, Thorsten ORCID logo; Mustaffa, Nur Ili Hamizah ORCID logo; Liisa, Kallajoki; Pahnke, Katharina ORCID logo
Publisher PANGAEA
Publication Year 2026
Funding Reference German Research Foundation https://doi.org/10.13039/501100001659 Crossref Funder ID 506141804 Biogeochemical cycling of selected potentially harmful (ultra-)trace metals (Tl, REE) in coastal environments; Ministry for Science and Culture of Lower Saxony https://doi.org/10.13039/501100010570 Crossref Funder ID VWZN3175 Coastal ocean darkening – Light availability in the past and future marine environment
Rights Creative Commons Attribution 4.0 International; Data access is restricted (moratorium, sensitive data, license constraints); https://creativecommons.org/licenses/by/4.0/
OpenAccess false
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 5770 data points
Discipline Biospheric Sciences; Ecology; Geosciences; Natural Sciences
Spatial Coverage (8.145 LON, 53.514 LAT); Jade Bay
Temporal Coverage Begin 2017-08-10T10:00:00Z
Temporal Coverage End 2017-09-21T09:52:00Z