Probing the [FeFe]-hydrogenase using muon spectroscopy
During our previous experiment on HiFi (RB1320541) we measured the ALC spectrum of the Fe2(µ-pdt)(CO)4(PMe3)2 model hydrogenase complex over multiple temperatures. The spectra were characterised by two broad features which we were able to assign to a bridging and a terminally muoniated species, with the former being the dominant. In the current application our goals are threefold: 1) we would like to extend the field region of the ALC spectrum in the solid state to hunt for the Δ1 resonances predicted by our DFT calculations, 2) continue our investigation of addition sites and dynamics in solution where isotropy will remove Δ1 resonances (which could be masking Δ0 resonances in the solid state), 3) measure muonium addition rates over a number of dilute concentrations using ALC line the broadening technique.
- 12
- ALC
- Al
- CN
- Chemistry
- Delta0
- F 10
- F 100
- F 1000
- F 10000
- F 10020
- F 10050
- F 10080
- F 10110
- F 10140
- F 10170
- F 10200
- F 10230
- F 10260
- F 10290
- F 10320
- F 10350
- F 10380
- F 10400
- F 10410
- F 10440
- F 10470
- F 10500
- F 10530
- F 10560
- F 10590
- F 10600
- F 10620
- F 10650
- F 10680
- F 10710
- F 10740
- F 10770
- F 10800
- F 10830
- F 10860
- F 10890
- F 10920
- F 10950
- F 10980
- F 11000
- F 11010
- F 11040
- F 11070
- F 11100
- F 11130
- F 11160
- F 11190
- F 11200
- F 11220
- F 11250
- F 11280
- F 11310
- F 11340
- F 11370
- F 11400
- F 11430
- F 11460
- F 11490
- F 11520
- F 11550
- F 11580
- F 11600
- F 11610
- F 11640
- F 11670
- F 11700
- F 11730
- F 11760
- F 11790
- F 11800
- F 11820
- F 11850
- F 11880
- F 11910
- F 11940
- F 11970
- F 1200
- F 12000
- F 12030
- F 12060
- F 12090
- F 12120
- F 12150
- F 12180
- F 12200
- F 12210
- F 12240
- F 12270
- F 12300
- F 12330
- F 12360
- F 12390
- F 12400
- F 12420
- F 12450
- F 12480
- F 12510
- F 12540
- F 12570
- F 12590
- F 12600
- F 12620
- F 12630
- F 12650
- F 12660
- F 12680
- F 12690
- F 12710
- F 12720
- F 12740
- F 12750
- F 12770
- F 12780
- F 12800
- F 12810
- F 12830
- F 12840
- F 12860
- F 12870
- F 12890
- F 12900
- F 12920
- F 12930
- F 12950
- F 12960
- F 12980
- F 12990
- F 13000
- F 13010
- F 13020
- F 13040
- F 13050
- F 13070
- F 13080
- F 13100
- F 13110
- F 13130
- F 13140
- F 13160
- F 13170
- F 13190
- F 13200
- F 13220
- F 13230
- F 13250
- F 13260
- F 13280
- F 13290
- F 13310
- F 13320
- F 13340
- F 13350
- F 13370
- F 13380
- F 13400
- F 13410
- F 13430
- F 13440
- F 13460
- F 13470
- F 13490
- F 13500
- F 13520
- F 13540
- F 13550
- F 13560
- F 13580
- F 13600
- F 13610
- F 13620
- F 13640
- F 13660
- F 13670
- F 13680
- F 13700
- F 13720
- F 13730
- F 13740
- F 13760
- F 13780
- F 13790
- F 13800
- F 13820
- F 13840
- F 13850
- F 13860
- F 13880
- F 13900
- F 13910
- F 13920
- F 13940
- F 13960
- F 13970
- F 13980
- F 14000
- F 14020
- F 14040
- F 14060
- F 14080
- F 14100
- F 14120
- F 14140
- F 14150
- F 14160
- F 14180
- F 14200
- F 14220
- F 14240
- F 14260
- F 14280
- F 14300
- F 14320
- F 14340
- F 14360
- F 14380
- F 14400
- F 14420
- F 14440
- F 14450
- F 14460
- F 14480
- F 14500
- F 14600
- F 14750
- F 14800
- F 14900
- F 150
- F 1500
- F 15000
- F 15050
- F 15200
- F 15350
- F 15400
- F 15500
- F 15600
- F 15650
- F 15800
- F 15950
- F 16000
- F 16100
- F 16200
- F 16250
- F 16400
- F 16500
- F 16550
- F 16600
- F 16700
- F 16800
- F 16850
- F 17000
- F 17150
- F 17200
- F 17300
- F 17400
- F 17450
- F 17500
- F 17500 0
- F 17600
- F 17700
- F 17750
- F 17800
- F 17900
- F 18000
- F 18000 0
- F 18050
- F 18100
- F 18200
- F 18300
- F 18350
- F 18400
- F 18500
- F 18600
- F 18650
- F 18700
- F 18800
- F 18900
- F 18950
- F 19000
- F 19100
- F 19200
- F 19250
- F 19300
- F 19400
- F 19500
- F 19550
- F 19600
- F 19700
- F 19800
- F 19850
- F 19900
- F 20
- F 20 0
- F 200
- F 2000
- F 20000
- F 20020
- F 20040
- F 20060
- F 20080
- F 20100
- F 20120
- F 20140
- F 20150
- F 20160
- F 20180
- F 20200
- F 20220
- F 20240
- F 20260
- F 20280
- F 20300
- F 20320
- F 20340
- F 20360
- F 20380
- F 20400
- F 20420
- F 20440
- F 20450
- F 20460
- F 20480
- F 20500
- F 20520
- F 20540
- F 20560
- F 20580
- F 20600
- F 20620
- F 20640
- F 20660
- F 20680
- F 20700
- F 20720
- F 20740
- F 20750
- F 20760
- F 20780
- F 20800
- F 20820
- F 20840
- F 20860
- F 20880
- F 20900
- F 20920
- F 20940
- F 20960
- F 20980
- F 21000
- F 21020
- F 21040
- F 21050
- F 21060
- F 21080
- F 21100
- F 21100 0
- F 21120
- F 21140
- F 21160
- F 21180
- F 21200
- F 21220
- F 21240
- F 21260
- F 21280
- F 21300
- F 21320
- F 21340
- F 21350
- F 21360
- F 21380
- F 21400
- F 21420
- F 21440
- F 21460
- F 21480
- F 21500
- F 21520
- F 21540
- F 21560
- F 21580
- F 21600
- F 21620
- F 21640
- F 21650
- F 21660
- F 21680
- F 21700
- F 21720
- F 21740
- F 21760
- F 21780
- F 21800
- F 21820
- F 21840
- F 21860
- F 21880
- F 21900
- F 21920
- F 21940
- F 21950
- F 21960
- F 21980
- F 22000
- F 22020
- F 22040
- F 22060
- F 22080
- F 22100
- F 22120
- F 22140
- F 22160
- F 22180
- F 22200
- F 22220
- F 22240
- F 22250
- F 22260
- F 22280
- F 22300
- F 22320
- F 22340
- F 22360
- F 22380
- F 22400
- F 22420
- F 22440
- F 22460
- F 22480
- F 22500
- F 22520
- F 22540
- F 22550
- F 22560
- F 22580
- F 22600
- F 22620
- F 22640
- F 22660
- F 22680
- F 22700
- F 22720
- F 22740
- F 22760
- F 22780
- F 22800
- F 22820
- F 22840
- F 22850
- F 22860
- F 22880
- F 22900
- F 22920
- F 22940
- F 22960
- F 22980
- F 23000
- F 23020
- F 23040
- F 23060
- F 23080
- F 23100
- F 23120
- F 23140
- F 23150
- F 23160
- F 23180
- F 23200
- F 23220
- F 23240
- F 23260
- F 23280
- F 23300
- F 23320
- F 23340
- F 23360
- F 23380
- F 23400
- F 23420
- F 23440
- F 23450
- F 23460
- F 23480
- F 23500
- F 23520
- F 23540
- F 23560
- F 23580
- F 23600
- F 23620
- F 23640
- F 23660
- F 23680
- F 23700
- F 23720
- F 23740
- F 23750
- F 23760
- F 23780
- F 23800
- F 23820
- F 23840
- F 23860
- F 23880
- F 23900
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- F 23940
- F 23960
- F 23980
- F 24000
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- F 24080
- F 24100
- F 24120
- F 24140
- F 24160
- F 24180
- F 24200
- F 24220
- F 24240
- F 24260
- F 24280
- F 24300
- F 24320
- F 24340
- F 24350
- F 24360
- F 24380
- F 24400
- F 24420
- F 24440
- F 24460
- F 24480
- F 24500
- F 24500 0
- F 24520
- F 24540
- F 24560
- F 24580
- F 24600
- F 24620
- F 24640
- F 24650
- F 24660
- F 24680
- F 24700
- F 24720
- F 24740
- F 24760
- F 24780
- F 24800
- F 24820
- F 24840
- F 24860
- F 24880
- F 24900
- F 24920
- F 24940
- F 24950
- F 24960
- F 24980
- F 2500
- F 25000
- F 25020
- F 25040
- F 25060
- F 25080
- F 25100
- F 25120
- F 25140
- F 25160
- F 25180
- F 25200
- F 25220
- F 25240
- F 25250
- F 25260
- F 25280
- F 25300
- F 25320
- F 25340
- F 25360
- F 25380
- F 25400
- F 25420
- F 25440
- F 25460
- F 25480
- F 25500
- F 25520
- F 25540
- F 25550
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- F 25580
- F 25600
- F 25620
- F 25640
- F 25660
- F 25680
- F 25700
- F 25720
- F 25740
- F 25760
- F 25780
- F 25800
- F 25820
- F 25840
- F 25850
- F 25860
- F 25880
- F 25900
- F 25920
- F 25940
- F 25960
- F 25980
- F 26000
- F 26020
- F 26040
- F 26060
- F 26080
- F 26100
- F 26120
- F 26140
- F 26150
- F 26160
- F 26180
- F 26200
- F 26220
- F 26240
- F 26260
- F 26280
- F 26300
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- F 26340
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- F 26400
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- F 26480
- F 26500
- F 26520
- F 26540
- F 26560
- F 26580
- F 26600
- F 26620
- F 26640
- F 26660
- F 26680
- F 26700
- F 26720
- F 26740
- F 26750
- F 26760
- F 26780
- F 26800
- F 26820
- F 26840
- F 26860
- F 26880
- F 26900
- F 26920
- F 26940
- F 26960
- F 26980
- F 27000
- F 27020
- F 27040
- F 27050
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- F 27080
- F 27100
- F 27120
- F 27140
- F 27160
- F 27180
- F 27200
- F 27220
- F 27240
- F 27260
- F 27280
- F 27300
- F 27320
- F 27340
- F 27350
- F 27360
- F 27380
- F 27400
- F 27420
- F 27440
- F 27460
- F 27480
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- F 27940
- F 27950
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- F 27980
- F 28000
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- F 28060
- F 28080
- F 28100
- F 28120
- F 28140
- F 28160
- F 28180
- F 28200
- F 28220
- F 28240
- F 28250
- F 28260
- F 28280
- F 28300
- F 28320
- F 28340
- F 28360
- F 28380
- F 28400
- F 28420
- F 28440
- F 28460
- F 28480
- F 28500
- F 28520
- F 28540
- F 28550
- F 28560
- F 28580
- F 28600
- F 28620
- F 28640
- F 28660
- F 28680
- F 28700
- F 28720
- F 28740
- F 28760
- F 28780
- F 28800
- F 28820
- F 28840
- F 28850
- F 28860
- F 28880
- F 28900
- F 28920
- F 28940
- F 28960
- F 28980
- F 29000
- F 29020
- F 29040
- F 29060
- F 29080
- F 29100
- F 29120
- F 29150
- F 29200
- F 29300
- F 29400
- F 29450
- F 29500
- F 29600
- F 29700
- F 29750
- F 29800
- F 29900
- F 3000
- F 30000
- F 30050
- F 30200
- F 3500
- F 4000
- F 4200
- F 4400
- F 4500
- F 4600
- F 4800
- F 50
- F 500
- F 5000
- F 5200
- F 5400
- F 5600
- F 5800
- F 6000
- F 6200
- F 6400
- F 6600
- F 6800
- F 70
- F 700
- F 7000
- F 7200
- F 7400
- F 7600
- F 7710
- F 7740
- F 7770
- F 7800
- F 7830
- F 7860
- F 7890
- F 7920
- F 7950
- F 7980
- F 8000
- F 8010
- F 8040
- F 8070
- F 8100
- F 8130
- F 8160
- F 8190
- F 8200
- F 8220
- F 8250
- F 8280
- F 8310
- F 8340
- F 8370
- F 8400
- F 8430
- F 8460
- F 8490
- F 8520
- F 8550
- F 8580
- F 8600
- F 8610
- F 8640
- F 8670
- F 8700
- F 8730
- F 8760
- F 8790
- F 8800
- F 8820
- F 8850
- F 8880
- F 8910
- F 8940
- F 8970
- F 9000
- F 9030
- F 9060
- F 9090
- F 9120
- F 9150
- F 9180
- F 9200
- F 9210
- F 9240
- F 9270
- F 9300
- F 9330
- F 9360
- F 9390
- F 9400
- F 9420
- F 9450
- F 9480
- F 9510
- F 9540
- F 9570
- F 9600
- F 9630
- F 9660
- F 9690
- F 9720
- F 9750
- F 9780
- F 9800
- F 9810
- F 9840
- F 9870
- F 9900
- F 9930
- F 9960
- F 9990
- Fe2 pdt CO 6 PMe3 2
- PMe3
- PMe3_0 7M
- T 10
- T 10 0
- T 100
- T 150
- T 150 0
- T 160
- T 170
- T 200
- T 25
- T 250 0
- T 280 0
- T 300 0
- T 50
- T 75
- TF
- TF20
- Ti
- background
- continued
- delta0
- field
- foils
- frozen
- liquid
- repolarisation
- scan
- search
- slits
- slits 12
- t20
- tf20
Provenance | |
---|---|
Creator | Dr Upali Jayasooriya; Professor C J Pickett; Dr Joseph Wright; Dr Jamie Peck; Dr Stephen Cottrell |
Publisher | ISIS Neutron and Muon Source |
Publication Year | 2018 |
Rights | CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/ |
OpenAccess | true |
Contact | isisdata(at)stfc.ac.uk |
Representation | |
---|---|
Resource Type | Dataset |
Discipline | Chemistry; Natural Sciences |
Temporal Coverage Begin | 2015-04-01T08:00:00Z |
Temporal Coverage End | 2015-05-03T04:05:08Z |