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Studies of Free Radical Final States on Au nanoparticles by RF-muSR and ALC S...
Small-sized metal nanoparticles (NPs) are of long standing interest to both magnetism and heterogeneous catalysis. Recent µSR studies of bare Au NPs encapsulated in mesoporous... -
muSR study of field-induced phases in a 1-dimensional Ising system
MV2O6 brannerites have a network structure in which chains of edge-sharing MO6 octahedra result in 1-dimensional magnetic properties. A recent study reported monoclinic CoV2O6... -
A GENERAL METHOD OF MEASURING ANTIOXIDANT CAPACITY
Antioxidants are very important molecules because they can prevent or slow down the oxidative damage to our bodies. When our bodies use oxygen, free radicals are released which... -
Probing the [FeFe]-hydrogenase using muon spectroscopy
During our previous experiment on HiFi (RB1320541) we measured the ALC spectrum of the Fe2(µ-pdt)(CO)4(PMe3)2 model hydrogenase complex over multiple temperatures. The spectra... -
Silicon nanoparticles in thermoelectric material applications - Solution stat...
In order to meet the UK's commitment to reduce 80% of greenhouse gas emissions by 2050, it is necessary make major advances in efficient, clean and secure energy conversion and... -
Probing the [FeFe]-hydrogenase subsite using muon spectroscopy
Previous ALC measurements of the Fe2(pdt)(CO)4(PMe3)2 and [Fe2(pdt)(CO)4(CN)2]2- (referred to as 1 and 2) model hydrogenase subsites have yielded some intriguing results (RB... -
ALC spectroscopy of the molecule BEDT-TTF and some of its salts
The electron donor molecule BEDT-TTF (ET) provides a versatile building block for constructing molecular metals, superconductors, magnets and quantum spin liquids. A common... -
Electron Spin Relaxation Studies In the 5,7-Br/Cl/I Substituted Aluminium- Hy...
We have recently performed high field ALC measurements on the polycrystalline Metal Tris(Hydroxy-quinolate), MQ3, series in order to further investigate the intrinsic electron... -
Green vs Black Tea Anti-oxidant Potency as a Function of Fermentation Complet...
Since ancient times it has been known that using boiling water to prepare tea ¿burns¿ the brew destroying the teas flavours & beneficial nutrients. One aspect of a ¿burnt¿... -
Electron Spin Relaxation Measurements of P3HS
Using muon spin relaxation and ALC resonance spectroscopy the electron spin relaxation and mobility of the polymer P3HS will be measured as a function of temperature. The... -
Muon Spin Relaxation and ALC Resonance in Magnetic and non-Magnetic Oxalate S...
Repolarisation and level crossing resonance will be studied for several different oxalate compounds where muon radical states are known to be formed. Such compounds form a... -
Models of the [FeFe]-hydrogenase active site: raising the symmetry
The [FeFe]-hydrogenase enzymes are some of the best catalysts know for generating hydrogen. We have an ongoing programme to understand how their chemistry works, and to... -
Organometallic Radicals
Avoided level crossing muon spin resonance (ALC-muSR) is an exceptional tool for determining the structure and probing the dynamics of radicals but there have been only a few... -
An ALC study of the organic ferroelectrics TTF-CA and TTF-BA
The study of organic ferroelectrics based on mixed-stack charge-transfer salts is currently a rapidly developing research field. These materials attract interest as highly... -
Field-induced Tomonaga-Luttinger Liquid phase in a spin ladder
The new molecular magnet bis(2,3-dimethylpyridinium) tetrabromocuprate (DIMPY) is a strong-leg spin ladder with a quantum critical point at 3.0(3) T separating a low-field... -
Quantum tunnelling of muonium via radical states in molecular solids
The extreme quantum nature of muons and muonium in condensed matter is the result of having a mass that is nine times lighter than that of a hydrogen atom. While this quantum... -
A search for the muoniated hydroxyl radical, OMu
The elusive OMu radical is believed to be formed by muonium reaction with nitrous oxide but has never been directly observed. It would be invisible to transverse-field muon spin... -
Interaction of N2O with Membranes Using µSR
Nitrous oxide, N2O, is an inhalant anaesthetic with a long history of use dating back to 1844. It is most commonly used as a light sedative in dentistry, or in child birth and... -
Anomalous temperature dependence of the ALC spectrum of polybutadiene
The relative importance of factors affecting the low temperature ALC spectra of organic molecular systems such as polymers and small molecules is a topical issue. Polybutadiene... -
Models of the [FeFe]-hydrogenase active site: high symmetry in a biologically...
The [FeFe]-hydrogenase enzymes are some of the best catalysts know for generating hydrogen. We have an ongoing programme to understand how their chemistry works, and to...
