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Ozonation of organic films at the air-water interface of atmospheric aerosol
The Earth¿s climate is strongly influenced by atmospheric aerosols. Organic surfactant films on these aerosols influences their size, optical properties and ability to act as... -
The gas-phase oxidation of mixed organic films at the air-water interface ¿ t...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic... -
Local Dynamics in End-Functional Poly(ethylenes)
Poly(ethylene)s carrying multiple end-functional groups on a single chain end have been prepared from polybutadiene, saturated with either hydrogen or deuterium. These materials... -
Local structures and dynamics of new functional oxides
The melilite family are new xoide ion conductors with high mobility at low temperatures. Average structures suggest that the ability of the structure to accomodate high levels... -
Changes to the structure of natural lung surfactant, and extracted proteins, ...
The presence of a monolayer of surfactant material at the air-water interface of the lung is crucial for respiratory function. It is well known that exposure to the ubiquitous... -
Spin dynamics in the 1/3rd magnetization plateau phase of a triangular quantu...
This experiment is part of our research programme to explore novel quantum phases and phase transitions induced by magnetic field in frustrated quantum magnets. The quasi-2D... -
Temperature Dependence of the Oxidation of Monolayers Under Atmospheric Condi...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic... -
Surface modification in heteropolymer blends.
In recent years we have had considerable success with the surface modification of amorphous and crystalline thermal plastic polymers using multi-end functional additives. In... -
Reversible B-H Bond Activation at Cationic Rh(III) Centres: Structural Charac...
Catalytic processes leading to the functionalization of organic molecules by boron-containing reagents are highly topical ¿ ranging from transition metal catalysed hydro- and... -
Temperature dependence of spin dynamics near quantum criticality in an Ising ...
This proposal is part of our research programme to explore the interplay of thermal and quantum fluctuations near zero-temperature quantum phase transitions. Here we apply for a... -
DPPC bilayer oxidation by aqueous singlet oxygen
Oxidation of membrane lipids by Reactive Oxygen Species, ROS, in cells may impact ageing, cell apoptosis and cancer. We propose to use our skills obtained studying the oxidation... -
Aggregation of Polar Multi-end Functional Polymers
Polar functional groups on polymer chains are of particular interest for applications in adhesion, printing, biocompatibility and mineralisation. We have created a series of... -
Penetration and reaction of hydroxyl radical into organic films at the air-wa...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects droplet size and optical properties, important climatic effects.... -
Ionic Liquid Aggregation in Polymers
Ionic liquid/Polymer mixtures, where the ionic liquid is the minority component are of particular interest for their potential as high temperature plasticisers and conducting... -
Monomer dynamics in polymer nanocomposites
We have recently shown that the addition of single walled carbon nanotubes produces a minimum in the diffusion coefficient with increasing nanoparticle concentration. Initially,... -
Matrix Effects on Polymer Surface Segregation
We have used neutron reflectivity and complementary techniques of ion beam analysis and contact angle to understand the adsorption behaviour of multi-fluoro end functional... -
Understanding Melt Phase Aggregation in Semicrystalline Polymer Blends
We have recently prepared and studied the surface properties of some well-defined multi-end functional polyethylenes. Whilst most of our surface studies indicate that these... -
Microemulsion Controlled Polymorph Crystallisation
Control of crystallisation is essential for many applications ranging from pharaceuticals to packaging and food preservation, yet remains extremely challenging. Recently we have... -
Does ozone initiate damage to the main pulmonary surfactant lipid, DPPC, or c...
Exposure to ozone gas can cause inflammation of the airways and breathing difficulties. The initial reaction of ozone is thought to be predominantly with lipids present in the... -
Telechelic Polymer - Homopolymer Blends
We have recently embarked on a new 1 year project funded by Michelin to explore the self-associatation and mechanical properties of telechelic rubbery materials. Such materials...
