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Understanding the spin-Peierls Transition in KTCNQ and derivatives
Motivated by work showing that magnetic coupling between TCNQ anions in potassium TCNQ (KTCNQ) can be changed simply by changing the aromatic substituents, we seek to qunatify... -
Frustration, quantum spin ices and quantum diffusion
This proposal aims to characterise the spin dynamics of three Pr-based pyrochlores that may be realisations of quantum spin ice materials. The lower moment and larger wave... -
DYNAMICS OF SURFACTANTS IN LUBRICATING OILS
In a recent series of successful experiments at PSI and ISIS we were able to demonstrate the possibility of measuring the rate of transfer of a small molecule (allyl alcohol)... -
RF μSR in the gas phase: understanding a ¿null¿ result
We have made a significant effort to develop Radio Frequency μSR (RF μSR) as a technique for spectroscopy of organic radicals in the gas phase. Realising this method... -
Muon Spin Relaxation studies of Ni2TCNQ, Ni(TCNQ)2 and related materials
Amorphous molecular magnetic materials Ni2(OA) (OA:organic acceptor) were reported to exhibit ferromagnetism with Curie temperatures >400K. This work is controversial as it... -
Muonium in alpha-boron
Previous muon experiments have identified a muonium state in the commonly occuring, but complex, beta rhombohedral form of elemental boron. To complement recent theoretical work... -
The effect of metal nanoparticles on the electronic structure of bound free r...
In recent years, the noble metals nanoparticles (MNPs) have been the subject of intense interest in areas of materials science, biotechnology, medicine and organic chemistry for... -
End-Game: Cornering Solvent Effects on H-Addition in Green Tea Anti-Oxidants
Our ongoing project to characterise radical scavenging by the green tea anti-oxidant EGCG and its D-ring analogue, (3,4,5-(OH)3-Bz) is near-complete. ALC-MuSR experiments on the... -
Development of Radio Frequency µSR as a Method for Determining Hyperfine Coup...
Radio Frequency µSR provides a direct method for accurately determining muon hyperfine coupling constants, Aµ, for muoniated radical species. The method complements the well... -
Probing the [FeFe]-hydrogenase subsite using muon spectroscopy
Solid state repolarisation measurements of [Fe2(µ-pdt)(CO)4(PMe3)2] (RB 1010177) showed a weak recovery at ca.15G, a strong recovery at ca.100G and what was thought to be a weak... -
Muon level-crossing resonances as a probe for studying antiferromagnets at pu...
We propose a set of measurements using the HiFi spectrometer in which muon level-crossing resonances are used to probe the internal field inside antiferromagnets in which the... -
Unconventional superconductivity in quasi-1D K_2Cr_3As_3 (QLCR)
Metallic systems with one-dimensional chain-like atomic structure can support unusual mechanisms for electron pairing leading to superconductivity. K_2Cr_3As_3 is one of a... -
Using muons to investigate the excitation spectrum in low-dimensional molecul...
We propose to use longitudinal field muon-spin relaxation to investigate the excitation spectrum of the most successful realizations of one- and two-dimensional antiferromagnets... -
Muon spin relaxation studies of KTCNQ and related compounds
Potassium tetracyanoquinodimenthane (KTCNQ) undergoes a spin-Peierls (SP) transition at 396K where a transformation from uniform to dimerised TCNQ- molecules in 1D columns... -
RF MuSR in the gas phase: The Search for a Radical State
The main spectroscopic technique for studying radicals in solids and liquids, ESR, cannot usually be used to study radicals of more than 3-5 atoms in the gas phase due to strong... -
Hunting for the low-temperature, low-field magnetization plateau in Tb2Ti2O7
Tb2Ti2O7 is a pyrochlore antiferromagnet that has previously been viewed as a spin liquid. This description fails to describe key features of its physics and more recently the... -
characterisation of muonium in functionalized acenes
We wish to measure the high field ALCs of a series of related functionalised acenes, to understand the role of the ligands on the electron spin relaxation, which is of...
