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Magnetic and Structural Studies on Oxychalcogenides
In this proposal we request 3 days of beam time on HRPD to study the structures (both atomic and magnetic) of a variety of oxychalcogenide phases: La2O2Se2Fe2O, Ce2O2Se2Mn and... -
Crystal and magnetic structures of new 2D and 3D oxyselenides La2O2Se2M (M = ...
In this proposal we request 4 days of beamtime on GEM to study four new transition metal oxyselenide materials. Two new layered oxyselenides, La2O2Se2Mn and La2O2Se2Fe have been... -
Measurement of Residual Strain within Be-CuCrZr HIP-Bonded Samples for Fusion...
The ITER fusion reactor features first wall panels, facing the fusion plasma, that comprise Be tiles, bonded to a CuCrZr heat sink. During bonding of these materials, residual... -
Controlled Assembly of Cationic Polythiophene-Surfactant Complexes
We intend to study the phase behaviour of 2 cationic polythiophenes, P3MAHT and P3ImiHT, in the presence of the perfluorinated surfactant potassium... -
Structure and Phase Transitions of XNbOP2O7, with X = ND4 and Rb
In this proposal we request 3 days of beam time on HRPD to study the structure and phase transitions of XNbOP2O7 (X = Rb and ND4). These materials have been shown to undergo... -
Characterisation of the impact of weakly polar interactions on the vibrationa...
The present proposal is part of a project to formulate a quantitative synergy between experiment and theory, complimenting the results the applicants have already established in... -
Residual strain measurements in a monocrystalline nickel-based superalloy tur...
Rafted microstructure has been observed in specific areas of a fully heat-treated blade at the end of the manufacturing process. The solution heat-treated blade is believed to... -
Aggregation behaviour in solution of cationic conjugated polymers and oligomers
We extend previous work on aggregates formed by cationic conjugated oligomers in water with surfactants and... -
Spin excitations in La2O2Fe2OSe2 ¿ A Mott insulator candidate
We propose to map out the spin excitations in La2O2FeOSe2 using the MARI chopper spectrometer on a powder sample. Although the structure of La2O2FeOSe2 has some similarities to... -
Cubic SnMo2O8 - a PTE Puzzle
Experiments (many at ISIS) using crystallographic methods, total scattering, inelastic neutron scattering and theory have provided a detailed picture of the origin of strong... -
Influence of rafted microstructures on the in-situ strain response of single ...
The proposed experiment concerns the role of microstructure on the high temperature deformation behaviour of single crystal Ni-base superalloys. This class of material is of... -
Controlled Assembly of Cationic Polythiophene-Surfactant Complexes
We intend to study the phase behaviour of 2 cationic polythiophenes, P3MAHT and P3ImiHT, inthe presence of the perfluorinated surfactant (C8 chain) PFOS and its hydrogenated... -
Pressure Effects on Proton Migration 3,5-pyridinedicarboxylic Acid
Hydrogen bonds are ubiquitous in materials across the chemical spectrum, from inorganic to biological. They influence the structure, the functionality, and therefore the... -
Characterisation of residual strains and recrystallisation of single crystal ...
Ni-base single crystal (SX) superalloys are advanced materials that are used in modern land-based gas turbine blades to achieve high operation performance. However localised... -
In-situ stress relaxation during heat treatment in sub-scale forgings of Nick...
Advanced materials such as polycrystalline Ni superalloys put increased pressure on developing appropriate thermomechanical procedures, which avoid the generation of large... -
Metal ion induced condensation of anionic fluorine-based conjugated polyelect...
In the proposed experiments we aim to characterise the structures of aggregate species formed when divalent metal ions, such as calcium(II), interact with the anionic conjugated... -
Understanding the role of lanthanides in magnetic oxyselenides: Pr2O2Fe2OSe2
This proposal requests time to investigate the influence of an applied magnetic field on the oxyselenide Pr2O2Fe2OSe2. A metamagnetic transition involving ordering of Pr3+... -
The microscopic structure of the acetone - chloroform azeotrope
The acetone - chloroform system is the classic textbook example of a negative-pressure azeotrope, i.e. the vapour pressures of the binary mixtures are lower than expected for... -
FRET-based Conjugated Polymer Macromolecular Switch for Bio-Anion Recognition
We intend to study the aggregation behaviour of the all-conjugated block catiocopolyelectrolyte PF2/6-P3MAHT in the presence of the biomacroanion guanosine triphosphate (GTP) in... -
Monitoring Gamma Prime Evolution in Superalloys using Small Angle Neutron Sca...
The aim of the experiment is to monitor the temporal evolution of gamma prime precipitates in three polycrystalline nickel base superalloys using Sans2D. This instrument is...