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Exploration of Magnetic Excitations at High Energy Transfers in Superconducti...
We propose to study two single crystals with nominal compositions Fe1.07Te and Fe1.18Te using the MAPS spectrometer. The amount of interstitial Fe controls the material¿s... -
Understanding the Pressure Response in Amines: Weak hydrogen-bonding vs Non-b...
Methylamines are an ideal chemical system to study in order to understand the effects of steric bulk and competing non-bonding interactions on hydrogen bonding at the networks... -
Structural phase transition in SnSe with ultra low thermal conductivity
SnSe has recently been reported to have very good thermoelectric performance. This is linked to an ultralow thermal conductivity and occurs in the B-phase (ZT > 2 above 800... -
Probing the binding of CO2 on supported aminosilane sorbents with INS
Fossil fuels are the main contributor to global energy consumption, which has increased the amount of atmospheric CO2, increasing the severity of climate change and health... -
Molecular and framework dynamics in CH3NH3PbBr3 - Raman and neutron scattering
Organic-inorganic perovskites have recently been shown to be potentially efficient and inexpensive photovoltaics. These materials undergo a series of structural transitions and... -
Investigating the ammoniation of light metal hydrides for hydrogen storage ap...
Light-metal hydride and amide systems are currently among the most promising materials for reversible hydrogen storage. In this proposal, we ask for 3 days on POLARIS or GEM to... -
How do modifiers affect performance in iron Fischer-Tropsch catalysts?
The applicants have recently completed a series of INS studies on a model iron Fischer-Tropsch catalyst. Given the recent huge invigoration of F-T catalysis due to future global... -
Understanding the mechanism of benzyl alcohol oxidation using supported Au-Pd...
This proposal is a continuation of RB1000003. The aim of the present experiment is to gain further insight into the mechanism of benzyl alcohol oxidation using supported Au-Pd... -
Spin gap and possible spin-dimer formation in Ce(Os1-xFex)2Al10 (X=0 to 1)
Our neutron study using MARI/MERLIN on Ce(Ru1-xFex) 2Al10 reveals very interesting magnetic excitations and a manuscript is ready to submit to PRB. In x=0 (TN=27 K) a... -
Can we use the H-H stretch of adsorbed dihydrogen to characterise materials?
The use of the J 0-to-1 rotational transition of dihydrogen has been extensively used to characterise the state if hydrogen in and on materials. The disadvantage of studying the... -
Strain/order parameter coupling and anomalous elastic properties of Sr(Ti,Zr)...
HRPD data will be collected in situ at low and high temperatures from perovskites belonging to the Sr(ZrxTi1-x)O3 solid solution which have recently been characterised for their... -
Neutron scattering studies of hydrogen rotational transitions in Ni-MOF-74
We propose to use MARI to look at the full rotational spectrum of H2 in Ni-MOF-74 obtaining the full momentum distribution for H2 only at the Ni metal site and one with partial... -
Formation of Ho2Ge2O7 Pyrochlore at High Temperature and Pressure
When synthesised at high pressure and temperature, holmium germanate adopts the pyrochlorestructure. Because of its geometry, materials with this structure often have exotic and... -
Solvent Segregation in Phase-Separated Li-NH3-MeNH2
We request 2 days on MAPS (or 3 days on MARI) to determine the extent of solvent segregation in a liquid-liquid phase-separated metal-amine: The Li-NH3-MeNH2 system. Recently we... -
Excitation spectrum of isotope-enriched Sr2IrO4
Sr2IrO4 is an important material in condensed matter physics, having been discovered to host a novel Jeff=½ Mott insulating state.Yet while magnetic fluctuations play a crucial... -
OSTEOMETRICS IN BURNED HUMAN SKELETAL REMAINS: ESTIMATING HEAT-INDUCED DIMENS...
This study aims at developing a reliable method for probing diagenetic alterations in human bones upon burning events, by INS spectroscopy. The results will be coupled to Raman... -
Define the crystal structures of lead-free ferroelectric, candidate multiferr...
We have a range of new structures in the lead-free ferroelectric, candidate multiferroic and SOFC cathode areas. The HRPD data will be used to define these new crystal... -
An INS investigation of Cu/ZnO catalysts for methanol synthesis via CO2 hydro...
The prospect of producing methanol via the hydrogenation of CO2 over copper based catalysts is an exciting area of research that has been invigorated by the realization that... -
Characterisation of Protons in Pyrochlore Electrocatalysts
This proposal is about understanding the atomic-scale structure of complex oxides that contain water or protons and that are used as electrocatalyts for water splitting. Such... -
The definitive Bi4Ti3O12: a textbook example of Hybrid-Improper Ferroelectricity
Bi4Ti3O12 is a well-known and studied layered perovskite; such phases are ferroelectrics, which have been used in random-acccess memories and other applications. Understanding...
