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Hydrogen interactions in framework materials : part deux
Hydrogen binding to coordinatively unsaturated metal sites (CUMCs) in metal-organic frameworks (MOFs) has been extensively studied in our group using neutron powder diffraction... -
More than the sum - oxidation behaviour of mixed fatty acid monolayers
Single molecule thin films of various surface-active species are found on the surface of water bodies from the sea down to microscopic spray droplets. These films affect the... -
Effect of reversing lipid head group charge on vesicular properties
Zwitterionic lipids such as phosphatidylcholine (PC) are major components of the membranes that compartmentalize organisms. Although there is a large literature on PC, cationic... -
The XY pyrochlore AFM:spin dynamics upon rare-earth dilution in Er2Ti2O7 (CON...
Er2Ti2O7 constitutes an experimental realization of the <111> easy-plane pyrochlore AFM and orders at 1.1 K into the theoretically predicted spin structure. However, the... -
Liquid structure of benzene-cyclohexane mixtures: A model of alkyl-aromatic i...
Understanding the energetics and structure of aromatic molecules (those containing benzene rings) is important to a large area of chemical science including protein and DNA... -
Shape- and depletant- induced assembly of nanocolloids in submicron channels
Understanding the behavior of colloidal nanoparticles in submicron channels is essential for a number of technological challenges including fracture healing, channel-transport... -
Anomalous Layer at a Nematic-Air Interface using Thin Films
The aim is to establish the nature of the surface layer of 8CB at the nematic-air interface by measuring neutron reflection from the n=8, 10 and 12 homologues of the nCB series... -
Speciation and complex-ion formation in protic ionic liquids
A broad fundamental understanding of the design and properties of ionic liquids underpins their developing and future applications, which include accessing cellulosic polymers... -
Structure of Colloidal Crystals Near a Solid Surface
The structure of colloidal crystals (dispersions of particles that spontaneously order in a regular array) is known to be influenced by solid boundaries. However there are few... -
Probing the kinetics of the formation of lipid, peptide and DNA/siRNA complex...
Complexes prepared from cationic, dichain lipid (L) vesicles, positively chargely targeting peptides (P) and negatively charged DNA (D) or siRNA (R), known as LPDs and LPRs... -
Purothionin binding to model fungal lipid membranes
Purothionins and defensins are basic, amphiphilic, cysteine-rich and low molecular weight plant defence proteins. These proteins are active against a broad range of... -
Vibrational properties of hydrogen in niobium oxide
Niobium oxide based compounds have superior catalytic properties. Research to get an inside into the physical properties of hydrogen is extremely difficult as hydrogen in Nb2O5... -
High Pressure Structure of Carbonic Acid
Recent published studies have identified a stable solid form of carbonic acid at high pressure. This proposal is for beamtime to collect the data to solve its crystal structure. -
Structure of multi-component mixed metal molybdates by neutron diffraction
Our general aim is to understand the defect structure of complex oxides in ternary oxide systems, which are known to be effective selective oxidation catalysts. For this purpose... -
Effect of calcium ions and ionic strength on model bilayer structure
Calcium ions have been shown in a preliminary experiment to have a dramatic effect on the thickness and structure of free supported bilayer films. In this proposal we... -
The role of biogenic amines in lipopeptide biofilm formation
Pore forming lipopeptides, such as Tolaasin, are produced by pathogenic mushroom bacteria, and are implicated in diseases such as ¿brown blotch¿ disease. They have potential... -
Characterization of P3HT:PCBM blends by SANS measurements
Blends of poly-3-hexyl-thiophene (P3HT) and 6,6-phenyl-C61 butyric acid methyl ester (PCBM) are the most promising candidates for active layers of plastic solar cells with high... -
Fluoride uptake by polyaniline films for water purification and remediation
The beneficial effects of fluoride are well known, but higher levels are dangerous to health. Existing remediation methods used to address the latter situation all have... -
Determination of nuclear quantum effects on the hydrogen adsorption in metal-...
Metal-organic frameworks represent one of the most studied options to store hydrogen for clean-energy applications. Nuclear quantum effects, and in particular zero-point... -
Impact of Stereochemistry and Diamine Structure on Absorption of Constructed ...
Chiral gemini surfactants containing stereogenic centers and two amphiphilic moieties, not only maintain the chiral properties, but also exhibit stronger aggregation properties,...
