Hydrogen interactions in framework materials : part deux

DOI

Hydrogen binding to coordinatively unsaturated metal sites (CUMCs) in metal-organic frameworks (MOFs) has been extensively studied in our group using neutron powder diffraction and low resolution inelastic neutron scattering(INS). We have shown that this dihydrogen binding can greatly enhance the hydrogen adsorption enthalpy in MOFs. However, the detailed picture for this binding is still under debate though the INS has given us useful information. However, to obtain the most valuable information on the adsoprtion characteristics of hydrogen at the distinct adsorption sites we require the use of very high resolution spectrometers. The excellent energy resolution and wide energy range available on TOSCA provides unique information unobtainable elsewhere.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24068682
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24068682
Provenance
Creator Dr Anibal Ramirez-Cuesta; Dr Craig Brown
Publisher ISIS Neutron and Muon Source
Publication Year 2012
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2009-06-05T11:32:50Z
Temporal Coverage End 2009-06-14T05:14:36Z