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Hydration structure of 5-phenyl tetrazolate in LCST ionic liquids
The interaction of water molecules with a model ammonium phenyltetrazolate ionic liquid will be studied to determine the dominant structures present as a function of water... -
Crystal and magnetic structures of new ruthenate perovskites
Ruthenate perovskites have a diverse range of electronic properties originating from electron-electron correlations within broad 4d bands. We have recently investigated the high... -
Direct measurement of the Au-D bond
Gold is historically thought of as an inert metal, and so investigation of its chemistry has been under-investigated. In 1986 it was shown that gold can be incredibly active as... -
Probing the structure of titanium silicates over a wide range of length scales
Titanium silicates are important for a number of applications such as ultra low expansion glasses, anti-reflective thin film coatings and catalytic materials. Titanium silicates... -
Disrupting structural correlations in the Na-Ca-NH3 system
Na or Ca, when dissolved in ammonia, yield metallic liquids. These liquids are fully miscible and yet each possesses a different intermediate-range order depending on the parent... -
Magnetostriction in (Bi, La)-orthoferrites
We have recently observed unusual magnetostrictive behaviour in Bi0.5La0.5FeO3 (BLFO), a phenomenon which is not present in either solid solution end member. This proposal seeks... -
Soft-templating of hard carbons to produce ordered and disordered Hard carbons.
Carbonized biowaste presents a promising route to producing energy materials in a carbonnegative way, given that the precursor material (i.e. plant material) relies on the... -
Molecular interactions of Paracetamol in solution
Active Pharmaceutical Ingredients (APIs) are frequently delivered to the patient in the solid state as part of an approved dosage form (e.g. tablets, capsules, etc.) Drug... -
The role of water in homogeneous catalytic processes mediated by water solubl...
A large number of chemicals are currently obtained by catalytic synthetic processes, but usually in most of these processes the catalyst remains in the reaction medium during... -
Measurement of residual stresses and stress relaxation during heat treatment ...
The understanding of residual stresses is essential to utilize materials properties and to optimize castings. Previous experiments showed a large deviation between simulated and... -
A model system to study the important interactions of proteins from extreme e...
Organisms which live in the presence of large quantities of salt are known as halophilic (meaningsalt-loving). Halophilic proteins are of great interest due to their ability to... -
Structure of protic ionic liquids mixed with formamide derivatives.
Mixtures of protic ionic liquids (PIL) and polar, protic molecular liquids (MLs) are attracting great attention. Due to the ionic nature of PILs and the role of hydrogen bonding... -
Multiscale time-resolving study of solid state crystallisation from the mesom...
We will exploit the unique capability of Nimrod in the study of the long standing issue of polymer crystallisation. We focus on isotactic polypropylene which has been quenched... -
Local microstructure investigations of lignin-derived hard carbon
Sodium ion batteries (NIB) are promising alternatives to the current lithium ion batteries: sodium is cheap, sustainable, and has similar properties to lithium. Search for an... -
Why is Choline Arginate the Best Performing Bio-IL for Biomass Pretreatment?
The ionic liquid choline arginate [Ch][Arg] is more effective for coal pretreatment than other choline based amino acid ILs, but the underlying mechanism is unclear.... -
Atomic and pore structure of amorphous zeolites
We will investigate a series of amorphised zeolitic solids and determine the short and medium range order structures and more importantly the nature of pore-size when we go from... -
Topochemically Reduced Complex Iridium Oxides
In recent years there has been a growing interest in modifying the anion lattice of complex transition metal oxides, via topochemical manipulation, to tune the magnetic and... -
NIMROD: Structural Investigation of Surfactant Coatings of FePt Nanocrystals
This proposal aims to investigate the short range structure and morphology of FePt NPs, of average diameter ~ 2 nm, and their surrounding surfactant layer (oleic acid and... -
Polyaromatic Hydrocarbons: Understanding liquid structure for benchmarking of...
Asphaltenes are a complex and problematic fraction of crude oil that can precipitate, alter wettability and stabilise unwanted oil-in-water emulsions. Asphaltenes have a high... -
Atomic and pore structure of hetero-atom substituted alluminophosphate materials
We will investigate a series of aluminophosphate systems, in particular related to small pore materials and determine the short and medium range order structures and more...
