Direct measurement of the Au-D bond

DOI

Gold is historically thought of as an inert metal, and so investigation of its chemistry has been under-investigated. In 1986 it was shown that gold can be incredibly active as a catalyst when present as nanoparticles. The field has since grown rapidly, and the investigation of gold as a catalysts has increased hugely. Recently, the presence of hydrogen bonded to gold has been confirmed, and this study aims to use total neutron scattering to characterise this bond. Measurement using deuterium rather than hydrogen should be easier and allow determination of the bond length for the first time.

Identifier
DOI https://doi.org/10.5286/ISIS.E.58449193
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/58449193
Provenance
Creator Dr Ivan da Silva Gonzalez; Dr Ian Silverwood; Dr Arun Chutia; Professor Stewart Parker; Professor Richard Catlow; Mr Scott Rogers
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-04-13T00:00:00Z
Temporal Coverage End 2015-04-15T00:00:00Z