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Proton ordering and hydrogen bonding in the hydrous zinc phosphate hopeite, Z...
We request 4 days of beamtime on SXD in order to locate the protons and quantify their ordering within the structure of hopeite Zn3(PO4)2.4H2O. Hopeite is an important phase in... -
Basic Science for Offpsec : Part 2
This proposal is part 2 of a set of two proposals on Offspec aimed at understanding some of the effects seen in off-specular data and in particular the use of the spin echo... -
IN-SITU NEUTRON DIFFRACTION STUDIES OF METAL-HYDRIDE HYDROGEN STORAGE MATERIALS
Recently [RB 900007], we have demonstrated that it is possible to determine the detailed site-by-site behaviour of hydrogen during in-situ absorption and desorption in metal... -
The hydration and ordering of lamellar block copolymer films prior to the for...
For polymer vesicles to act as effective molecular delivery systems we must efficiently encapsulate a molecular payload within the vesicle. We would like to use neutron... -
Investigating the reduction kinetics of high molecular weight metal oxides in...
There is a pressing worldwide need for research to develop specific sustainable spent fuel reprocessing technologies suitable for minimizing waste from next generation nuclear... -
Pd, Ni, V, Nb and Ti capping layer clamping effects in hydrogen cycling in Ca...
We ask for 8 days of beam time on CRISP to study the absorption and desorption of hydrogen and deuterium in Ti/Mg/Pd trilayer samples. Our specific objective is to understand in... -
A high pressure structural study of the charge transfer complexes trimethylam...
We propose a high-pressure powder neutron diffraction study of the archetypal donor-acceptor complexes (CD3)3N...I2 and (CD3)3N...ICl . These are the simplest structurally... -
Low Temperature Ordering in ZrMn2+xD3 Superstochiometric Deuterides
ZrMn2H3 is a Laves Phase intermetallic hydride with interesting materials properties - unlike most Laves Phases, the parent alloy ZrMn2 is not a line phase but has a wide range... -
Inelastic Neutron Spectroscopy Study of Ammonium Borohydride
Ammonium borohydride (ABH2) has been studied as a hydrogen storage material, it stores hydrogen on both cationic and anionic sites and has the largest gravimetric and volumetric... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
Gas-phase oxidation of insoluble monolayer at air-water interface with no equ...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic... -
Development of a Novel Low - Intermediate Temperature Solid Proton Conductor
The compound, Si5O(PO4)6, is a component of a solid phosphoric acid catalyst, it has highly unusual coordination of the silicon (octahedral, as well as the more common... -
Inelastic Spectroscopy of the Mobile Phase of Ammonia Borane
Ammonia borane (AB) is one of the most promising hydrogen storage materials. There has recently been work on a more mobile phase of AB (denoted AB*) which is formed (via the... -
Crystallographic determination of the minting of coins in Tudor Britain : an ...
King Henry VIII's flagship, the Mary Rose, offers a unique insight into Tudor life. As well as her value as one of the first purpose built warships of the modern period,... -
A METHOD OF MEASURING ANTIOXIDANT CAPACITY
Antioxidants are receiving increased attention for their potential effects in the prevention of chronic and degenerative diseases such as cancer and cardiovascular disease as... -
Muonium in alpha-boron
Previous muon experiments have identified a muonium state in the commonly occuring, but complex, beta rhombohedral form of elemental boron. To complement recent theoretical work... -
Competition between C-H---O hydrogen bonds and C=O----Br halogen bonds
Our main objective in this proposal is to study the competition between halogen and hydrogen bonding as a function of temperature in the complex (CH3)2C=O--- Br2. The results of... -
Vibrational properties of ammine complexes
Our intention is to study the INS spectra of ammine complexes nNH3LiBH4 (with n = 1,2,3,4) and nNH3LiI (n=1). Ammine complexes (MXm(NH3)n), amides (M(NH2)m), and imides... -
The Interaction of Ammonia with Binary and Ternary Deuterides;
The interaction of ammonia with binary hydrides (prototypically, the interaction of LiH with ammonia gas) is thought to be the predominant interaction for hydrogen production... -
Copy of: Towards a Method of Quantifying Electrophilicity and Nucleophilicity
Our understanding of chemical reactivity is founded on the fundamental concepts of Electrophilicity and Neucleophilicity. There are a number of attempts of limited applicability...
