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In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Oxide ion vacancy distribution in A site substituted defect pyrochlores.
Electrolytes based on pyrochlores such as Ln2M2O7 (M = Ti, Zr, Hf) have attracted attention due to their relative stability combined with relatively high ionic conductivity at... -
Vibrational properties of hydrogen in niobium oxide
Niobium oxide based compounds have superior catalytic properties. Research to get an inside into the physical properties of hydrogen is extremely difficult as hydrogen in Nb2O5... -
Programme Access Rosseinsky/Claridge
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The application of INS to investigate the methanol-to-gasoline reaction over ...
As part of a UK Catalysis Hub initiative in Catalyst Design involving a team of academic and industrial researchers, the methanol-to-gasoline reaction over zeolite catalysts is... -
Mass-selective Neutron Spectroscopy of Molten FLiBe
We request time on VESUVIO to study the properties of FLiBe using mass-resolved neutron spectroscopy (MANSE). FLiBe is a mixture of BeF2 and LiF and its physical properties in... -
Variable Temperature Study of Structural Transitions Occurring In Clusters of...
Catalysts lower energy costs of a wide range of important processes, from the production of oil and plastics to the preparation of drugs and paints, making these products... -
Total Scattering Study of Hexagonal and Rhombohedral Bi2O3 Based Electrolytes
Bismuth oxide based electrolytes have been widely studied due to their high oxide ion conductivity. The d-phase of Bi2O3 shows the highest known oxide-ion conductivity of any... -
Magnetic structure determinenation in the antiferroelectric - antiferromagnet...
This proposal seeks to explore a multiferroic material new to science, that of the antiferroelectric ¿ antiferromagnetic ceramic Bi0.8Nd0.2FeO3. This new class of material is of... -
In-situ neutron diffraction studies on proton conducting oxides (CaxLa1-x) ~6...
Rare-earth tungstates have recently attracted significant attention due to its high-temperature proton or mixed proton-electron conductivity. The proton conductivity in La6WO12... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
Superstructure in bismuth rich substituted bismuth oxides
A study of superlattice ordering in substituted bismuth oxides is proposed. Bismuth rich compositions at the 14:1 B:M (where M = W/La and Ta) ratio will be investigated. These... -
The structure and thermoelastic properties of jadeite, NaAlSi2O6, above room ...
Jadeite, NaAlSi2O6, is a rare, but geologically important clinopyroxene. In the upper part of the transition zone between the upper and lower mantle most pyroxenes are... -
Structure/Conductivity Relationship in Doped Bismuth Tantalate Solid Electrol...
A detailed study of the temperature and compositional variation of defect structure in doped bismuth tantalates is proposed. Tantalum doping into Bi2O3 can achieve d-phase... -
Ba3MoNbO8.5 novel oxide ion conductor: Direct observation of oxide ion dynamics
Oxide ion conductors are researched as electrolytes in solid oxide fuel cells. Yttria-stabilized zirconia is the currently used electrolyte in SOFCs, leading to high operating... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Phase behaviour in lanthanum antimony niobate proton conductors
Antimony substituted lanthanum niobium oxide is a recently developed proton conductor with potential use in fuel cells, gas sensors and steam electrolysers Our preliminary work... -
INS study of the first carbon-carbon bond formation stage in the methanol-to-...
Methanol-to-Hydrocarbons is an industrially relevant reaction. The generally accepted mechanism under steady state is the 'hydrocarbon pool' mechanism with the hydrocarbons... -
Determination of the structure of methoxy on eta-alumina
We have recently demonstrated that we are able to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this is a... -
Hydrothermal synthesis and calcination of hydrotalcites
Hydrotalcites are anionic clays which have a variety of applications, including use as environmentally friendly catalysts and catalyst precursors. In this experiment we propose...