-
In-situ Gravimetric Study of the Decomposition of Alkali Metal Amidoboranes
We request 3 days on HRPD with the IGAn apparatus, to perform in-situ neutron diffraction and thermogravimetric studies of the decomposition of deuterated alkaline amidoboranes.... -
Investigation of Graphitic Carbon Nitride (g-C3N4) structure
Production of hydrogen from water via visible light driven photocatalytic water splitting is a future technology that may offer important routes to clean fuels. Graphitic carbon... -
In-situ studies of amides with ammonia
The aim of this proposal is to determine that materials that are present in the ammoniation of amides. -
Investigation of effect of radiolytic oxidation on A3-3 matrix material micro...
A3-3 matrix material is the semi-graphitc composite used in high-temperature nuclear reactors to form fuel compounds containing coated particle fuel. In a CO2 cooled reactor,... -
HIGH RESOLUTION NEUTRON DIFFRACTION STUDIES ON NEW POLYMORPHS OF MAGENSIUM TE...
The development of high energy density and high efficiency hydrogen storage materials is widely considered to be one of the most challenging barriers to the adoption of fuel... -
Phase retrieval for non-trivial systems
Neutron reflectometry (NR) is a very powerful technique for the study of thin layers. It is able to measure composition, thickness and roughness and is a very penetrating... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Investigation of molecular rotation and disorder in methylamine borane (CH3NH...
We request 3 days on TOSCA to study molecular rotations of NH4+ and BH4- ions and the ionic disorder in ammonium borohydride (rock salt lattice) and its methylated derivative.... -
Structural studies of the cycling and decomposition of Mg(NH3)6(BH4)2
Given its high hydrogen gravimetric density, ammonia may be utilised as a hydrogen carrier, and thus ammonia stores are an area of interest. It is known that Mg(BH4)2 takes up... -
W I F David - Energy Project
W I F David - Energy Project -
In-situ reflectometry studies of hydrogen cycling in Mg/Ti multilayers
We ask for 3 days of beam time on CRISP to study the absorption and desorption of hydrogen and deuterium in two Mg/Ti multilayer samples. Our specific objective is to understand... -
Characterisation of diffuse scattering in β-Ti GUM metal
The goal of this proposal is to measure the diffuse scattering in Beta-Ti Gum Metal. We have measured the phonon dispersion curves and have found several soft-phonon anomalies... -
Muon states in black phosphorus
Our recent experiment showed that muons implanted into black phosphorus (the most stable allotrope of the element, with a low band gap of 0.3eV) are apparently diamagnetic, with... -
The Pressure and Temperature Dependence of the Structure of Ammonium Triiodide
We have shown that the molecular ionic solids MI3 (M=Tl, Cs, Tl, NH4) undergo structural phase transitions below 3.4 GPa at RT to give the same new high pressure phase (HP) with... -
Investigating the ammoniation of light metal hydrides for hydrogen storage ap...
Light-metal hydride and amide systems are currently among the most promising materials for reversible hydrogen storage. In this proposal, we ask for 3 days on POLARIS or GEM to... -
Composition depth profiling of novel spray-coated plastic solar cell materials
We propose to study a range of new lower energy gap organic photovoltaic (OPV) materials deposited by spray coating using neutron reflectivity. The new materials to be studied... -
Depth profiling the composition of multilayer organic solar cell thin films
We propose to study thin-film blends of the polymer:fullerene system PTB7:PC70BM using neutron reflectivity (NR). This system currently exhibits the highest power conversion... -
The hydration and ordering of lamellar block copolymer films prior to the for...
The key to the use of polymer vesicles as effective molecular delivery systems is in the ability to efficiently encapsulate a molecular payload within the vesicle. We would like... -
Kinetics of Protein Adsorption on well-characterised polymer brushes
We wish to develop a rational understanding of the mechanisms underlying the way water soluble polymer brushes - in particular those of polyethylene oxide/polyethylene glycol -... -
A high pressure structural study of the charge transfer complexes of pyridine...
We propose a high-pressure powder neutron diffraction study of the simple donor-acceptor complexes (C5D5N)...ICl and (C5D5N)...IBr . These are the simplest structurally...