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Identifying the mechanism behind spin relaxation in organic materials
We wish to measure the low-field ALCs of a series of related functionalised acenes to identify which mechanism (spin orbit or hyperfine) is responsible for spin relaxation in... -
Separating static and dynamic contributions to the muon relaxation in Ca3(Co,...
Ca3CoMnO6 has alternating ions in ferromagnetic Ising chains that are antiferromagnetically coupled on a triangular lattice and realizes an important model in frustrated... -
Decoupling the spin fluctuations with high magnetic fields in the geometrical...
Gadolinium gallium garnet (GGG) is a frustrated system which has already been successfully studied using muons. This study extends the earlier work to high magnetic field and... -
Characterisation of Green-Tea Radical Scavengers by ALC-MuSR and High-Level C...
We propose to characterise selected radical structures of the green-tea anti-oxidant flavenoid EGCG (& selected analogues), by DFT/post-HF computation and ALC-MuSR, towards... -
Level crossings in the open ring molecular magnet Cr8Cd
Molecular nanomagnets (MNMs) comprise clusters of exchange coupled transition metal ions which often have a negative anisotropy constant, favoring a ground state with a large... -
End-Game: Cornering Solvent Effects on H-Addition in Green Tea Anti-Oxidants
Our ongoing project to characterise radical scavenging by the green tea anti-oxidant EGCG and its D-ring analogue, (3,4,5-(OH)3-Bz) is near-complete. ALC-MuSR experiments on the... -
Towards a validated standard method for performing DFT calculations of muoniu...
In this proposal we want to address the issue of the identification of the different muonium adducts that are possible in Alq3 without any crystallographic constraints, and... -
The effect of metal nanoparticles on the electronic structure of bound free r...
In recent years, the noble metals nanoparticles (MNPs) have been the subject of intense interest in areas of materials science, biotechnology, medicine and organic chemistry for... -
Spin dynamics in the Tomonaga-Luttinger liquid system SrCo2V2O8
SrCo2V2O8 is believed to belong to the same rare universality class as Tomonaga-Luttinger liquids, which may be descrived by the 1D XXZ model. In SrCo2V2O8, this is accomplished... -
ALC studies of solid benzene
For muoniated radical spectroscopy studies, benzene has long been the classic prototype system. However most of these studies have been at higher temperatures, often in the... -
Electron spin relaxation measurements in polymeric systems
This proposal looks to study the electron spin relaxation using high field ALC measurements in two polymers, which differ only by the non-metal (i.e S or Se) in the polymer... -
Effect of electric field on paramagnetic state formation in molecular semicon...
The effect of electric field on the diamagnetic and paramagetic muon spin rotation signals will be investigated for the organic molecular semiconductors NPB and TPBi . These... -
Interaction of Xe with Membranes Using µSR
The mechanism of action of inhalation anaesthetics such as N2O and the inert gases are unclear. Direct binding to receptor sites on membranes would rely on weak intermolecular... -
The role of spin-orbit interaction on Group-III-trisquinolates
Spin based electronics (spintronics) is one of the most exciting and challenging areas in nanotechnology. It is expected to be of major scientific and social impact. Very little... -
Muon radicals in the metastable phases of Sulphur
Following our investigation of alpha-orthorhombic sulphur, we will measure level crossing spectra of some other allotropes and phases, to find if the muon radical observed in... -
muSR in the presence of significant spin-orbit coupling
The great majority of known muonium defect centres and muonium substituted organic radicals have essentially spin-only magnetism, with few exhibiting any noticeable departure... -
RF μSR in the gas phase: understanding a ¿null¿ result
We have made a significant effort to develop Radio Frequency μSR (RF μSR) as a technique for spectroscopy of organic radicals in the gas phase. Realising this method... -
Identification and dynamics of muon states in octabutoxy-phthalocyanine
The current experiment proposes to identify and study the spin dynamics of the muon states formed in octabutoxy-phthalocyanine (oBu-H2Pc) using the avoided level crossing... -
Vibrations of a muoniated radical center and photochemistry in benzophenone
Benzophenone is an ideal material to study vibrations of a muon radical centre with near-IR laser light, as all C=O bonds in solid state are almost parallel to each other and it... -
Decoupling internal fields in a magnetically ordered sample
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