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Copy of: Determination of the population of sp2 and sp3 bond lengths in graph...
The aim of this proposal is to examine the relative population of sp2 and sp3 bonds in a small number of graphitic samples, given that the bond length is 1.42A for standard sp2... -
Probing the structure of titanium silicates over a wide range of length scales
Titanium silicates are important for a number of applications such as ultra low expansion glasses, anti-reflective thin film coatings and catalytic materials. Titanium silicates... -
Long-Range and Local Structures of New Pyrochlores and Fluorites
We propose to study by total neutron scattering the structures of some complex oxide materials prepared by new hydrothermal routes in order to construct structural models... -
Structure-Property Relationships in Polymorphs of Mn(CN)2
We will determine the atomic and magnetic structure of two polymorphs of manganese cyanide, Mn(CN)2, which exhibit negative thermal expansion (NTE). The two forms are related;... -
Test experiment: Neutron diffraction on helium in silica
We request 3 days of beamtime on GEM to attempt to perform neutron diffraction on helium inside vitreous SiO2. Significant amounts of helium can be dissolved into the glass... -
The Nature Of Zinc Substitution in Beta-Tricalcium Phosphate
We have a long established interest in the materials used for the immobilisation of nuclear waste from the domestic power industry and legacy waste from various defence... -
A structural study of titanium tellurite glasses
Tellurite glasses exhibit strong non-linear properties which are related to the asymmetric environment of the Te atom. The non-linear optical effects are strongest when the Te... -
Evaluation of inelasticity effects in diffraction
For total diffraction measurements using neutrons it is important to correct the data for inelasticity effects, especially for samples containing light atoms. Conventionally... -
The Structure of Alkaline Earth Germanate Glasses
We request GEM beamtime to study the structure of a series of calcium germanate glasses. The changes in coordination number and properties which occur in alkali germanate... -
Isotopic Mass Contrast Study of Silica Glass
We wish to perform neutron diffraction measurements on glass samples of SiO2 and 30CaO.70SiO2 containing both natural oxygen and 18O. The oxygen scattering lengths are almost... -
Structural studies of modified iron phosphate glasses to understand key struc...
We intend to use neutron diffraction and x-ray diffraction to investigate the structure of potassium and barium iron phosphate glasses, which are potential candidate systems for... -
Structure-Property Relationships in Photoluminescent Platinum and Palladium C...
The average and local structure in the mixed-metal cyanides, Ni1/2Pt1/2(CN)2, Ni1/2Pd1/2(CN)2 and Pd1/2Pt1/2(CN)2 will be determined to give the M-C and M-N bond lengths, the... -
The environment of lithium in an invert glass
We request beamtime to study lithium silicate glasses over a very wide composition range from 20 to 65 mol.% Li2O, made by rapid quenching. For the higher Li2O contents, the... -
A systematic survey of solute-solute contacts in bulk metallic glasses
A clear description of the local atomic structure as a function of the composition is essential to guide discovery and development of new metallic glasses. The efficient cluster... -
Neutron Training Course 2013
Neutron Training Course 2013 Thursday 7th March 2013 Friday 8th March 2013 Wednesday 13th March 2013 -
Structural Models of the Polymorphs of Gallium Oxide
Gallium oxide is an apparently simple oxide that has been reported to exist as at least 5 polymorphs all of which are stable at room temperature. Structural models, however, for... -
Polyhedra Coexistence in Alkali Borogermanate Glasses
GeO2-rich potassium borogermanate glasses are topologically complex, in that [BOn] (n = 3, 4) and [GeOn] (n = 4, 5, 6) polyhedra may all coexist. We wish to determine average... -
Metastable phase formation and memory effects in barium borate glasses.
BaB4O7 glass crystallises to different polymorphs of the same composition depending on the prior thermal history of the glass and the surface area of the sample. This indicates... -
Structures of Gel Precursors of Nanoporous Materials
Nanoporous zeolites are well-known materials with huge industrial and commercial application in important areas yet their crystallisation mechanism remains under great debate.... -
The structural role of zinc in complex phosphate glasses for new bone cements
A study of zinc containing phosphate glasses for biomedical applications is proposed. The structural role of zinc as a function of composition will be investigated through...