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Texture characterisation in hot deformed two-phase titanium
This proposal is aimed at investigating the crystallographic texture evolution that occurs during hot forging of two-phase alpha/beta titanium alloy Ti-64, widely used in... -
The possibility of strongly ferromagnetic austenite in a stainless steel
It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =... -
Cation site disorder in KTiOPO4 isostructures
KTiOPO4 (KTP) is a well known non-linear optical material. Its crystal structure has highly asymmetric Ti-O bonds, a rigid TiO6-PO4 lattice and K cations trapped in cages. The... -
Relaxor-like dielectric behaviour in stoichiometric Sillenite Bi12SiO20
We request 1 day of beam-time on POLARIS to collect Neutron Diffraction (ND) data on the Sillenite Bi12SiO20 (gamma-Bi2O3) that we have recently discovered to exhibit a... -
Pressure effect on high-temperature multiferroic CuO studied by a single crys...
We propose to perform neutron diffraction experiment under high pressure condition, using a single crystal of CuO on WISH beamline. This monoxide is known as a multiferroic... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
Improper ferroelectricity in hexagonal tungsten bronzes
We address the detailed atomistic mechanism of ferroelectricity in a new family of oxides typified by the composition CsNbW2O9. Contrary to the mechanism in most ferroelectrics,... -
The role of Disorder in Phase Transitions in some manganese Perovskites
The aim of this work is to understand the origin of the difference in the behaviour between the two doped manganites Sr0.65Pr0.35MnO3 and Sr0.70Ce0.30MnO3. The hypothesis we... -
The ferroelectric phase transition in Dion-Jacobson layered perovskites - con...
Ferroelectricity in the Dion-Jacobson (DJ) family of layered perovskites arises from a 'trilinear coupling', whereby two non-polar lattice modes interact in such a way to... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Understanding Chemical Expansion in Perovskite Oxides: Impact of Long-Range D...
"Chemical expansion" occurs when some ceramics expand upon releasing oxygen. Their ability to effectively "breathe" oxygen makes them of use in sustainable energy... -
Possible high-temperature polar phases in the [110] layered perovskites NdBaI...
Geometric ferroelectrics are an unusual and rare class of materials which exhibit spontaneous electrical polarisation due purely to 'geometric' effects, i.e. caused by atomic... -
Investigating the ammoniation of light metal hydrides for hydrogen storage ap...
Light-metal hydride and amide systems are currently among the most promising materials for reversible hydrogen storage. In this proposal, we ask for 3 days on POLARIS or GEM to... -
Probing the structure of calcium silicates over a wide range of length scales.
Sol-gel derived calcium silicates are of great importance due to their ability to bond to bone and stimulate new bone growth. Diffraction has revealed the atomic-scale changes... -
Strain/order parameter coupling and anomalous elastic properties of Sr(Ti,Zr)...
HRPD data will be collected in situ at low and high temperatures from perovskites belonging to the Sr(ZrxTi1-x)O3 solid solution which have recently been characterised for their... -
Investigation of the multiferroic materials Ba3Dy2GaNb9O30 and Ba3.5Dy2Ga1.5N...
We have recently performed a ZF muon experiment on Ba3Dy2GaNb9O30 in EMU under the influence of electric fields and demonstrated that this material demonstrates multiferroic... -
Thermal expansion of kyanite, andalusite and sillimanite
Al2SiO5 forms three naturally-occurring polymorphs, kyanite, andalusite and sillimanite. These minerals are produced by varying degrees of metamorphism of sedimentary rocks, the... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
IN-SITU NEUTRON DIFFRACTION STUDIES OF METAL-HYDRIDE HYDROGEN STORAGE MATERIALS
Recently [RB 900007], we have demonstrated that it is possible to determine the detailed site-by-site behaviour of hydrogen during in-situ absorption and desorption in metal... -
Gas condensation and fluid behaviour in nanoporous ZIF-8 materials upon gate...
This proposal aims to study condensation transitions in nanoporous flexible materials by means of wide Q-range neutron diffraction. We plan to perform an in-situ gas...