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Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
In situ diffraction studies of cathode materials for Li ion batteries
Li-ion batteries are interesting because they offer high power and, as a consequence, they are preferred to aqueous-based batteries for traction applications e.g. hybrid... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Investigating the ammoniation of light metal hydrides for hydrogen storage ap...
Light-metal hydride and amide systems are currently among the most promising materials for reversible hydrogen storage. In this proposal, we ask for 3 days on POLARIS or GEM to... -
Muon Spin Relaxation detection of Spin-Polarized Conduction Electrons in Silicon
The proposed experiment is to observe optical spin-injection in Silicon through MuSR detection. An important part of research in next generation electronics focusses on the... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
In-situ diffraction studies of ammonia decomposition over iron, ruthenium and...
We request 3 days beam time on POLARIS for the in-situ study of the crystalline phase composition of iron, manganese and ruthenium catalysts for ammonia decomposition. These... -
Combined in-situ structural and hydrogen desorption/absorption studies of hyd...
The Li?N?H hydrogen storage system is one of the most promising candidates for hydrogen storage in vehicular applications and the addition of halide ions significantly increases... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Building a comprehensive understanding of cation ordering in the commercial c...
The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
Impact of Jahn-Teller Distortions in Sr0.5Pr0.5MnO3
We propose to use the HRPD to establish the sequence of structures, and the nature of the transitions between these, in two complex manganites Sr0.5Pr0.5MnO3 and... -
Unidentified Phase Transition in Polar Lanthanum Tantalate (LaTaO4)
The family of crystals with formula ABX4 represent a very interesting class of ferroelectrics that are extremely two-dimensional. Fluorides have been extensively researched but... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
Investigation of a frustrated quantum magnet with novel interaction scheme
SrCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions that are coupled into network of isolated triangles,a highly frustrated hyperkagome lattice consisting of... -
In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Investigating the formation of novel mixed amide-imide complexes and understa...
Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of... -
The chemical interaction and confinement effect of molecules in the sol-gel A...
Owing to the separation in the mesoscale and confinement effect of mesostructured pores to the molecule, mesoporous materials have been widely applied as matrices of host-guest... -
Investigation of a Potential realization of the Nersesyan-Tsvelik Model in (N...
We propose to investigate the highly one-dimensional (1D) S=1/2 Heisenberg antiferromagnet (NO)[Cu(NO3)3] which is a potential realization of the Nersesyan-Tsvelik model. The...
