Unidentified Phase Transition in Polar Lanthanum Tantalate (LaTaO4)

DOI

The family of crystals with formula ABX4 represent a very interesting class of ferroelectrics that are extremely two-dimensional. Fluorides have been extensively researched but there is great potential for oxides of this class, such as LaTaO4, due to oxides being favoured for device applications. Studies have reported the evolution of morphologies of LaTaO4 with temperature, but one phase transition at ~200ºC is accompanied by an anomalously small peak in permittivity, which suggests the transition is unusual. Variable temperature XRD of this material has revealed a change in lattice parameters which coincide with the phase transition but this is suspected to be a consequence of a shift in oxygen positions. It is then suggested that by using HRPD, the change in oxygen positions can be observed across the phase transition and hence the structural distortion can be characterised.

Identifier
DOI https://doi.org/10.5286/ISIS.E.98019521
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/98019521
Provenance
Creator Dr Jonathan Gardner; Dr Alexandra Gibbs; Dr Finlay Morrison; Professor James Scott; Mr Grant William Howieson
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2018-10-13T07:00:00Z
Temporal Coverage End 2018-11-17T18:14:34Z