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Local and intermediate-range order in AgI-containing glasses
Usual structural hypothesis related to superionic glasses containing metal halides MY = LiI, NaBr, AgI, etc., implies the absence of chemical interactions between the host glass... -
Sodium chalcohalide glasses for battery applications
Lithium batteries provide the highest energy density which makes them ideal candidates for future generations of portable electronics and electric vehicles. The increasing... -
Atomic structure of mercury iodide and mercury chalcohalide liquids
Optical applications of chalcogenide glasses need a wide transparency window. Promising glass systems include HgI2. Our recent studies of the yHgI2 (1-y)As2X3 glasses, where X =... -
Mercury sulphide dimorphism in liquids and glasses
A waste majority of crystals exists in several polymorphic forms in different domains of the P,T-diagram. Liquids and glasses also exhibit polyamorphism and the question remains... -
Atomic structure of 2NaY-Ga2S3 (Y = Cl, Br, I) liquids
Alkali halide sulphide and selenide glasses MY-Ga2X3-GeX2 (M = Li, Na, Rb, Cs; Y = Cl, Br, I; X = S, Se) are promising hosts for active and passive optical devices, solid-state... -
Glasses and supercooled liquids in the Se-Cl system
Little is known on the structure and properties of vitreous Se doped with halogens in contrast to group III, IV, V, and VI dopants and also many metal additives. Our Raman... -
Molecular As-rich sulphur glasses
AsxS1-x binaries belong to the most studied chalcogenide glassy systems. The glass-forming region in the system was found to be rather limited, 0.05 < x < 0.43, caused by... -
Mercury Sulphide Dimorphism in Thiogermanate Glasses
Crystalline mercury sulphide exists in two drastically different polymorphic forms: red chain-like insulator, alpha-HgS, and black tetrahedral narrow-band semiconductor,... -
Atomic structure of mercury chalcohalide glasses
Optical applications of chalcogenide glasses need a wide transparency window in far IR. Promising glass systems include HgI2. We have synthesised three vitreous systems... -
P4Se3 polyamorphic glasses synthesised at high-pressure
PxSe1-x glasses cover almost entire composition range from pure Se to P0.84Se0.16. In addition, red phosphorus is usually also amorphous. The P4Se3 cage compound, situated in... -
Sodium chalcohalide glasses for battery applications
Lithium batteries provide the highest energy density which makes them ideal candidates for future generations of portable electronics and electric vehicles. The increasing... -
Chemical disorder and network structure of glassy As2Te3
Telluride glassy systems are widely used for phase-change optical recording. They are also promising materials for far-IR applications. The atomic structure of telluride glasses... -
Hybrid glassy chalcogenides with non-centrosymmetric HgI2 molecules
Non-linear optical (NLO) crystals are widely used in advanced photonic technologies for second harmonic and difference frequency generation (SHG, DFG), producing coherent light... -
Structural changes in 320GB Blu-ray disc based on BiOx glass
Japanese company TDK has recently developed a 320GB optical storage disc. In contrast to usual DVDs and BDs, the 320GB TDK disc seems to operate because of difference in... -
Structure of novel silica-free titanate glasses
Silica-free barium titanate bulk glasses, containing lanthanide elements, show unusually high dielectric response and a high refractive index. These properties allow crucial... -
Preferential Conduction Pathways in Sodium Conducting Glasses for Battery App...
The ionic conductivity of sodium chalcogenide or chalcohalide glasses is 2 to 3 orders of magnitude higher than that of oxide glasses and comparable with lithium ionic... -
Atomic structure of amorphous alumina Al2O3
Solid alumina Al2O3 has many industrial applications. Recently it was found that porous anodic alumina film formed by anodizing aluminium in an appropriate acidic/alkaline... -
Mixed alkali environment in chalcohalide glasses for optical applications
Heavy alkali halide sulphide and selenide glasses are promising hosts for active and passive optical devices. Lithium and sodium chalcohalide glasses exhibit high ionic... -
Metal Halide Induced Chemical Disorder in Chalcogenide Glasses
Chalcogenide glasses containing light alkali and Group 11 (Cu, Ag) halides MY (Y = Cl, Br, I) exhibit high ionic conductivity while their heavy alkali counterparts show...
