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Kinetics and Structure of Butanone Hydrogenation in the Presence of a Water S...
Over 75% of all chemicals and fuels require the use of a catalyst in their generation. However, despite their ubiquity, very little is known on the atomic and molecular... -
Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Characterising the amorphicity and porosity of ice aggregates in planet-formi...
With the discovery of almost 3000 exo-planets it is clear that planet formation is a by-product of star formation, yet in the micron ? cm size range, where relative velocities... -
Composition dependent structure in mixtures of water and hydrogen bonded mono...
This is part of a project concerning the interplay between water and other H-bonded liquids using a range of complementary experimental techniques, e.g. dielectric spectroscopy,... -
Structural investigations of low-temperature "trapped solutions" of C60 fulle...
We propose a series of neutron scattering measurement to determine the water structure in amorphous H2O/C60 fullerene vapour deposits. We believe that these samples, prepared by... -
Defects and Medium-Range Disorder in the Metal¿Organic Framework UiO-66
We wish to use NIMROD to study the distribution and nature of defect sites in the high-thermal-stability metal-organic framework UiO-66. For the most part, defect structures in... -
Ion Binding in Tetradecyltrimethylammonium Surfactant Micelle Solutions
This proposal continues our studies of surfactant micelles using NIMROD, to obtain previously inaccessible details of headgroup-ion interactions. In our previous experiments... -
Silica perturbation of the water structure around cationic micelles during te...
This proposal continues a new direction in our research on surfactant-templated inorganic materials. These nanostructured materials contain ordered arrays of surfactant micelles... -
Understanding Structural Changes in Amorphous Solid Water (ASW) on Heating
This experiment will establish the structural changes that occur in Amorphous Solid Water (ASW) prior to the process of pore collapse or crystallisation. We will study the... -
Delivery of Mixtures of Volatile Organic Compounds by Capillary Condensation ...
Condensation is the phenomenon of turning vapour into liquid, and this happens differently in open and confined spaces. The latter occurs under lower vapour pressure, and is a... -
Structural Resolution of Colloidal Iron Nanoparticles used in Clinical Applic...
We propose to use the NIMROD diffraction instrument to produce high-resolution data on the structure of various nanoparticulate iron oxide-hydroxides. Although widely used in a... -
PEG-Deep Eutectic Solvents for Nanoparticle Synthesis
Deep Eutectic Solvents (DES) are complexes of organic salts and neutral hydrogen bond donors. They are tuneable, low volatility liquids that are environmentally benign and which... -
Towards Neutron Scattering of Amorphous Materials in the Gigapascal Regime
Over the past few years, extensive developments have been made in the use of neutron diffraction for structural studies of liquids and amorphous materials at high pressure.... -
Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Photo-catalytic oxidation of phenol over porous TiO2: A Modulation excitation...
Solar energy is an abundant renewable source to tackle energy and environmental concerns. For example, solar energy can be converted into electricity, can be used to produce...
