Dynamics of Poly Dimethyl Amino Ethyl Methacrylate / water glycerol mixtures

DOI

We want to study the microscopic mechanisms of solvent dynamics such as water and glycerol in ahydrophilic polymer. Dielectric measurements suggest that below the glass transition temperature(Tg) of the mixture water dynamics are confined in the polymer solution, while above Tg,cooperative-like dynamics are observed. The Quasi-Elastic Neutron Scattering (QENS) experimentsproposed here (selective to the component dynamics via deuterium labeling) will provide valuablespatial information to characterize and further understand the polymer and solvent dynamics.The objective of this proposal is to study the picosecond time scale dynamics for solutions ofsolvent-polymer mixtures. In order to separate the relative contributions of both, polymer andsolvent, isotopic labeling will be exploited by using deuterated solvent and polymer, respectively.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24079439
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24079439
Provenance
Creator Dr Remi Busselez; Professor Arantxa Arbe
Publisher ISIS Neutron and Muon Source
Publication Year 2013
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2010-05-13T08:09:01Z
Temporal Coverage End 2010-08-04T08:54:04Z