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Negative thermal expansion in the rutile phase of ZnF2
It has recently been discovered than the rutile phase of zinc fluoride shows negative thermal expansion along all three crystallographic axes. What is highly unusual about this... -
Proton dynamics in novel organic ferroelectric materials
The vast majority of known ferroelectrics are inorganic compounds such as barium titanate and potassium dihydrogen phosphate. Contrary to naïve expectation, ferroelectricity in... -
Inelastic neutron scattering study on the Spin-Lattice interaction in the Spi...
AB2O4 is one of the most investigated systems due to the interaction between electron, spin, orbital, and lattice, which lead to the anormal physical properties:a) the orbital... -
Intra-block magnetic excitations in KFe0.8Ag1.2Te2
KFe0.8Ag1.2Te2 is made of 2x2 squares of Fe atoms, upon lowering temperature the system spontaneously undergoes a transition that breaks the fourfold rotational symmetry. A... -
Is dynamic asymmetry the essential ingredient in the (universal?) 'strong-fra...
We want to elucidate whether the so-called ¿strong-fragile¿ transition reported for water mixtures is a universal phenomenon driven by confinement effects originated by the... -
Magnetic ordering in CaFe3O5 and CaFe5O7
This proposal is to explore the evolution of magnetic ordering in two members of the homologous series CaFe2O4(FeO)n with n = 1, & 3, and to correlation the behaviour of the... -
High Resolution Powder Diffraction of Manganites to Determine Bond Lengths as...
Manganites show promise as magnetocaloric materials - for use in solid-state refrigeration - in terms of cost, durability and tunable thermal conductivity. By tuning the... -
Multiferroic (Ferroelastic/Magnetic) Phase Transitions in KMnF3
KMnF3 perovskite undergoes 3 structural, and two magnetic phase transitions on cooling from 300 K to 2 K. Above 185 K the compound is in the aristotype structure, on cooling... -
Aza-crown-stabilized Alkali-Alkalide Systems: Solvent and metal effects on di...
We request 4 days on IRIS to investigate the diffusional and rotational dynamics of the alkalide forming, fully methylated aza-crown hexamethyl-hexacyclen (HMHC) in... -
Atomic structure of formamidinium lead iodide perovskite
New perovskite phases containing lead and halogens with a molecular cation are providing new options for materials in solar cells, giving unusually high efficiencies in... -
Neutron diffraction and µSR investigation on YbPd
YbPd crystallizes in the cubic CsCl-type structure and reported to have magnetically ordered ground state with the mixed valence of the Yb ion. Further, it under goes through... -
In-situ hydrogen decomposition studies of ammonia borane and the diammoniate ...
Ammonia borane (AB) is one of the most promising hydrogen storage materials. We have extensively studied the low temperature behaviour of this material This proposal asks for 3... -
Inelastic neutron scattering study quantum criticality of Ba(Fe1/3Co1/3Ni1/3)...
Exotic finite-temperature collective excitations beyond standard Landau Fermi liquid framework exhibit anomalous temperature dependences in the transport and thermodynamic... -
Superstructures in lithium cobaltate
The battery material LixCoO2 has recently been shown to have high thermopower comparable to NaxCoO2 at high x. In the case of NaxCoO2 we showed using neutron Laue diffraction on... -
Neutron Diffraction study of Highly Frustrated SrEr2O4
We propose to measure the neutron diffraction pattern of a single crystal sample of SrEr2O4, using the WISH diffractometer. As the magnetic Er ions in this compound are linked... -
Magnetic structure and multiferroicity in metal-formate perovskites
The family of guanadinium metal formates (M=Mn, Fe, Co, Ni, Cu) are isostructural with the perovskites and are therefore of interest for potential applications: in particular,... -
Examining the properties of water channel in an organic matrix.
The objectives are to study the interaction of water molecules held in a channel in an organic matrix. We have structurally characterised a water tetramethylpiperididine complex... -
Structural phase diagram of rare earth substituted multiferroic BiFeO3 - revi...
BiFeO3 is the most widely studied multiferroic and rare earth doping overcomes problems associated with phase metastability and leakage which have hampered applications. We... -
Study of magnetic spiral in the room temperature multiferroic BiFeO3 - PbTiO3
BiFeO3 is a room temperature multiferroic, displaying both ferroelectric and antiferromagnetic (AFE) ordering. x-BiFeO3 - (1-x)-PbTiO3 is also multiferroic at room temperature... -
Oxygen Positional Disorder in the "Empty" Tetragonal Tungsten Bronze Ba4La0.6...
Ferroelectric tetragonal tungsten bronze oxides (TTBs) have been extensively studied for their application dielectric and non-linear optical devices. TTBs often exhibit...
