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Proton dynamics in novel organic ferroelectric materials
The vast majority of known ferroelectrics are inorganic compounds such as barium titanate and potassium dihydrogen phosphate. Contrary to naïve expectation, ferroelectricity in... -
Magnon dispersion in the polar ferrimagnet BaCaFe4O7
Polar or non-centrosymmetric ferri(-o)magnets offer a plethora of potential technological devices;the inherent magnetoelectric effect can underpin both pyroelectric or... -
Multiferroic (Ferroelastic/Magnetic) Phase Transitions in KMnF3
KMnF3 perovskite undergoes 3 structural, and two magnetic phase transitions on cooling from 300 K to 2 K. Above 185 K the compound is in the aristotype structure, on cooling... -
Study of magnetic spiral in the room temperature multiferroic BiFeO3 - PbTiO3
BiFeO3 is a room temperature multiferroic, displaying both ferroelectric and antiferromagnetic (AFE) ordering. x-BiFeO3 - (1-x)-PbTiO3 is also multiferroic at room temperature... -
Study of structural phase transition in the spin-dimer YbAl3C3 using high res...
YbAl3C3 undergoes a structural phase transition at 80 K and a spin-dimer formation below 10K. To gain more information on the nature of the spin-dimer state and the phase... -
Variable Temperature Study of thallium and caesium azides
This proposal seeks to investigate the effect of temperature on the structures of thallium and caesium azide. High-resolution neutron powder diffraction data are necessary to... -
A Self-consistent Description of the Thermoelastic Properties of Dielectric P...
20 years ago, Anderson proposed that the thermoelastic properties of the dominant (mantle) phase within the Earth, MgSiO3 perovskite, could be described as a simple Debye solid.... -
Strain analysis of commensurate charge order/zener polaron ordering transitio...
High resolution powder diffraction data will be used to obtain lattice parameter and atomic coordinate variations as a function of temperature for Pr0.6Ca0.4MnO3, which has a... -
Magnetic structure of pyrochlore irridate Y2Ir2O7
We propose to study by powder neutron diffraction the ordered magnetic state of the pyrochlore compound Y2Ir2O7. There is currently an increasing interest in the condensed... -
From giant magneto-elastic coupling to negative thermal expansion
We recently used high-resolution neutron diffraction on HRPD to observe the largest magneto-elastic coupling ever seen in a metallic magnet. The material studied was CoMnSi, a... -
A total scattering study of the phase transitions in the hybrid organic-inorg...
Hybrid organic-inorganic perovskites are interesting candidates for a range of applications, from solar cells to light emitting diodes and lasers. For the latter applications... -
Multiferroic (Ferroelastic/Magnetic) Phase Transitions in KMnF3
KMnF3 perovskite undergoes 3 structural, and two magnetic phase transitions on cooling from 300 K to 2 K. Above 185 K the compound is in the aristotype structure, on cooling... -
Probing Magnetic Interactions in LnOH(CO3) Paramagnetic Magnetocalorics
Local magnetic interactions in lanthanide compounds have recently been shown to tune their entropically driven magnetocaloric effect (MCE), useful for magnetic coolants. In this... -
Well, well, well: the free energy landscape of hydrogenated La(Fe,Si)13?
Magnetic cooling promises efficiency savings at room temperature but requires rapid cycling of a magnetic refrigerant in a magnetic field. Refrigerants with first order... -
The role of Disorder in Phase Transitions in some manganese Perovskites
The aim of this work is to understand the origin of the difference in the behaviour between the two doped manganites Sr0.65Pr0.35MnO3 and Sr0.70Ce0.30MnO3. The hypothesis we... -
Electronically-driven structural transition in Ti-doped Ca3Ru2O7
The purpose of the experiment is to determine the effect of titanium doping on the structural and magnetic transitions of Ca3Ru2O7. The pure material undergoes a Néel transition... -
The effect of redox on the substitution mechanism of Ti in meteoritic hibonite
We request 3 days of beam-time on HRPD to identify the substitution mechanism of Ti3+ and Ti4+ in synthetic hibonites [CaAl12O19]. The experiment forms part of a larger... -
Polycarbonate and tetramethyl bisphenol A polycarbonate
The miscibility of polycarbonates (PC) with polystyrene (PS) appears to be closely related to chain dynamics. Among all polycarbonates, tetramethyl bisphenol-A polycarbonate... -
Structures and magnetism of chemical and electrochemical deintercalates of la...
We propose to use POLARIS to perform two related experiments. Firstly we will investigate the structures and compositions of derivatives of some layered Mn/Cu oxysulfides which... -
Neutron diffraction characterization of gallium ferrite thin films
Ga2-xFexO3 (GFO) is a ferrimagnetic magnetoelectric material presenting a Curie temperature above room temperature for x>1.3. It is therefore an interesting candidate for the...