The Interaction of Ammonia with Binary and Ternary Nitrides

DOI

We request 2 days on GEM in conjunction with the IGAn apparatus to investigate the formation of lithium amide (LiNH2) from the interaction of Li3N with ammonia (ND3), and the formation of lithium amide and magnesium amide (Mg(NH2)2) from the interaction of lithium magnesium nitride (LiMgN) with ND3. Recent work at ISIS, in collaboration with the University of Oxford, has highlighted a new synthesis route for lithium amide, whereby lithium nitride interacts directly with ammonia to form lithium amide. A preliminary neutron diffraction study of the formed lithium amide using the GEM diffractometer at ISIS identified its stoichiometry to be Li1.23ND1.77, confirming the thermogravimetric observations. This material is the first ever reported ordered lithium amide with super-stoichiometry in lithium.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24079970
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24079970
Provenance
Creator Dr Devashi Adroja; Dr Martin Jones; Dr Simon Johnson
Publisher ISIS Neutron and Muon Source
Publication Year 2013
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2010-02-28T16:15:22Z
Temporal Coverage End 2010-03-01T11:38:38Z