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Investigation of the dynamics within the destabilised multi-component hydroge...
There is great interest in destabilised multicomponent hydrogen storage materials as this allows the reduction of the temperature of dehydrogenation while maintaining a... -
The Interaction of Ammonia with Binary and Ternary Nitrides
We request 2 days on GEM in conjunction with the IGAn apparatus to investigate the formation of lithium amide (LiNH2) from the interaction of Li3N with ammonia (ND3), and the... -
The solution structure of the OmpF¿Colicin N complex in neutral detergent by ...
Gram negative bacteria cause a wide range of diseases. Colicins are protein toxins capable of penetrating the outer membrane barrier and killing the bacteria. Thus they... -
The solution structure of the OmpF¿Colicin N complex in neutral detergent by ...
Gram negative bacteria cause a wide range of diseases including meningitis, bubonic plague, gonorrhoea, diarrhoea, Legionnaires' disease and cholera. Their outer membrane... -
Structural Studies of Li(ND3)n11BD4
On exposure to ammonia, Li(11)BD4 forms the ammoniate Li(11)BD4(ND3)n. Our recent experiment (RB820252) has shown that there are four distinct crystalline phases in the... -
Nuclear Structures of Lithium Substituted Layered Transition Metal Oxide Cath...
Novel cathode materials for rechargeable batteries have been under intense investigation since high cost and toxicity of current Li-ion batteries. We propose to study the... -
Long-range magnetism in spin, charge, and orbital ordered Pb3Mn7O15
Manganese oxides have attracted great interest in solid-state physics research owing to the diverse range of electronic ordering phenomena. Pb3Mn7O15 is a relatively... -
Charge disproportionation and structural modulation in multiferroic CaMn7O12
Multiferroic materials in which strongly coupled magnetic and ferroelectric order parameters coexist attract considerable interest. Below 90 K, CaMn7O12 possesses the largest... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Structural studies of the cycling and decomposition of Mg(NH3)6(BH4)2
Given its high hydrogen gravimetric density, ammonia may be utilised as a hydrogen carrier, and thus ammonia stores are an area of interest. It is known that Mg(BH4)2 takes up... -
Pressure Effects on Proton Migration 3,5-pyridinedicarboxylic Acid
Hydrogen bonds are ubiquitous in materials across the chemical spectrum, from inorganic to biological. They influence the structure, the functionality, and therefore the... -
High Longitudinal Field Relaxation in LiYHoF4
We have observed an anomalous monotonically increasing longitudinal field relaxation rate in LiY_(1-x)Ho_xF_4 for applied fields above 1000 G (along the c-axis) and at a... -
Magnetic phase diagram of multiferroic GdMn2O5
In the last five years, we have carried out a comprehensive study of the family of REMn2O5 multiferroics by neutron and X-ray magnetic scattering, providing details about the... -
Magnetic ordering in the frustrated honeycomb antiferromagnet Li2IrO3
This proposal is part of our research programme to explore novel ground states in frustrated quantum magnets. Strong spin-orbit coupling is predicted to stabilize composite... -
Determining the structure of the colicin OmpF complex
Large multiprotein complexes are the new frontier in structural biology. Individual proteins may be solved by X-ray crystallography but the relationships between subunits and... -
Solution Structure of the OmpF-TolA complex
Gram negative bacteria cause a wide range of diseases including meningitis, bubonic plague, gonorrhoea, diarrhoea, Legionnaires' disease and cholera. Their outer membrane... -
A search for transverse phonons in DNA
We have begun an experimental program to investigate the denaturing of DNA, using scattering techniques, to test statistical mechanical models for the moelcule. It is believed... -
Low Temperature Ordering in ZrMn2+xD3 Superstochiometric Deuterides
ZrMn2H3 is a Laves Phase intermetallic hydride with interesting materials properties - unlike most Laves Phases, the parent alloy ZrMn2 is not a line phase but has a wide range... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
Vibrational properties of ammine complexes
Our intention is to study the INS spectra of ammine complexes nNH3LiBH4 (with n = 1,2,3,4) and nNH3LiI (n=1). Ammine complexes (MXm(NH3)n), amides (M(NH2)m), and imides...