Elucidating sodium diffusion mechanisms in layered sodium transition metal oxides

DOI

Affordable large-scale energy storage systems with improved capacity are crucial to a sustainable energy future, and the great availability of Na in sea water makes Na-ion batteries a very attractive choice for stationary energy storage. A promising class of cathode materials for applications in Na-ion batteries are the layered sodium transition metal oxides, NaMO2 (M = Fe, Co etc.). We set out to generalise our QENS analysis (which already accounts for coherency effects) to mixed coherent and incoherent scatterers, such as Na. NaFeO2 is chosen as a starting point due to its electrochemical activity, simple structure as well as low incoherent scattering contributions from the static lattice. Understanding the diffusion mechanisms in this simple layered material is vital for subsequent successful investigations on more complex systems (containing multiple transition metals).

Identifier
DOI https://doi.org/10.5286/ISIS.E.98000325
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/98000325
Provenance
Creator Dr Jeff Armstrong; Dr Julia Wind; Mr Halvor Høen Hval; Dr Federico Bianchini; Dr Helmer Fjellvag; Dr Øystein Slagtern Fjellvåg; Mr Rasmus Thøgersen
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-10-02T08:00:00Z
Temporal Coverage End 2018-10-12T08:04:54Z