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Polymer chain conformations in solutions for electrospinning
This proposal is part of a research programme which is focused on nano-fibres prepared by electrospinning. The programme is centered on developing an understanding of the... -
Structures and magnetism of chemical and electrochemical deintercalates of la...
We propose to use OSIRIS to investigate the changes in magnetic ordering which occur when a series of layered oxysulfides with mixed-valent Mn ions in their oxide layers are... -
Molecular dynamics and melting in CH3NH3PbCl3:
The organic-inorganic perovskites (CH3NH3Pb(Br,Cl,I)3) have been identified as efficient photovoltaic materials. Theoretical calculations have suggested that the low energy... -
In-Situ Quasi-Elastic Neutron Scattering Study of a Gas Loaded Indium-Carboxy...
We request 8 days on IRIS to study the diffusion of adsorbed H2 gas and C2-hydrocarbons molecules within a gated indium-based porous metal-organic framework (MOF) as a function... -
The Effects of Zeolite Expansion on Molecular Diffusion
Zeolites are porous materials that can absorb other molecules, which makes them useful in a number of fields. When they absorb molecules, they change size, either shrinking or... -
Experimental evidence for quadrupolar order in the heavy fermion compound Ce3...
This proposal aims to probe the quadrupolar order believed to exist in the heavy fermion compound Ce3Pd20Si6 (CPS). Two phase transitions have been uncovered (in zero applied... -
QENS studies of improved hydrogen release in nanostructured ammonia borane fi...
Increasing the density of hydrogen storage is critical for the commercial introduction of hydrogen vehicles. Our nanostructured electrospun ammonia borane (AB)-polystyrene (PS)... -
Spin Frustration in a Novel Molecular FeIII_7 Propeller
The hepta-nuclear Fe(III) title compound Fe7 exhibits a unique antiferromagnetic exchange topology reminiscent of a three-bladed propeller, giving rise to spin frustration, also... -
Spin orientation in natural nanoscale intergrowths and the origin of giant ex...
The orientation of spins in a natural sample of Ti-bearing hematite (Fe2O3) has been measured previously from 2-300K using neutron powder diffraction. It was shown that spins... -
Li-ion diffusion in the solid electrolyte LLT
The high voltage and energy density has made lithium-ion batteries ubiquitous in portable electronics, such as iPods, laptops and mobile phones. At present, they are typically... -
Structures and magnetism of layered cobalt oxide selenide tellurides
This proposal aims to exploit the high resolution of HRPD and OSIRIS to probe the structures of the solid solution Ba2CoO2Cu2(Te1-xSex)2. The compound Ba2CoO2Cu2Te2 shows... -
The dynamics of water and terephthalate in layered double hydroxide clay
In this proposal we would like to study the dynamics of interlayer species in hydrotalcite clay: (a) water and (b) terephthalate anions. In the case of water, the aim is to... -
Magnetic Excitations in Magnetic Molecule {Mo214V30}
We propose to conduct inelastic neutron scattering (INS) measurements on deuterated polycrystalline samples of the magnetic molecule {Mo214V30}, to determine the low-lying... -
Magnetic structure of heavily Fermion TbxYb1-xAgGe
YbAgGe has an enhanced electronic specific heat coefficient and two magnetic phase transitions at TM1=0.8K and TM2=0.65K. We have grown a series of TbxYb1-xAgGe and YbAgGe... -
Correlation of structure and magnetic ordering with composition in layered co...
We propose to use OSIRIS to determine the magnetic structures of a series of cobalt oxysulfides containing Co in square planar coordination. Several compositions... -
Dynamical Transitions in the Ogg Glasses
We request 4 days on IRIS to study the temperature dependance of the structural dynamics in amorphous sodium-ammonia (Na-NH3). This will be the first investigation of the... -
Structural Investigation of Co-polymer and Comb-polymer Solid State Electroly...
This proposal regards studies of the structure and morphology of polymer electrolytes which can be used in Li-batteries. These electrolytes are effectively used in electric... -
Structure, thermal expansion and vibrational properties of ammonium bicarbona...
Ammonium carbonates, sensu lato, have relevance to carbon capture schemes and as potential hydrogen storage materials. These compounds occur on Earth as minerals and, since... -
Magnetism, structure and superconductivity in Sr1¿xNaxFe2As2 (OSIRIS)
We will use the high resolution of HRPD and the excellent long d-spacing data available on OSIRIS to investigate the phase transitions in Sr1-xNaxFe2As2 which are associated... -
Elucidating sodium diffusion mechanisms in layered sodium transition metal ox...
Affordable large-scale energy storage systems with improved capacity are crucial to a sustainable energy future, and the great availability of Na in sea water makes Na-ion...
