Comparison of Dynamical Behaviour in MAPbX3 and FAPbX3: How Do They Differ ?

DOI

Organic-inorganic lead halide perovskite compounds are shown to be very promising candidates for low cost, solution-processable, highly efficient (>22%) solar cells with a short energy payback time. The interesting feature of these materials is the presence of an organic molecular ion at the A site of the ABX3 structure. Many of the remarkable properties of the halide perovskites have been attributed to the dipolar nature and the dynamic behaviour of these cations. Therefore dynamics of molecular motion is an important prerequisite for mechanistic explanations of the outstanding optoelectronic properties of these systems. Methylammonium lead hallide (MAPbX3) and formamidinium lead hallide (FAPbX3), X=I, Br, Cl, has been the subject of great interest. We would like to investigate the dynamical behaviour of these systems using quasielastic neutron scattering technique.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1910317-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/105598354
Provenance
Creator Professor Dipankar Das Sarma; Dr Ramaprosad Mukhopadhyay; Dr Veerendra K SHARMA; Dr Victoria Garcia Sakai
Publisher ISIS Neutron and Muon Source
Publication Year 2023
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2020-02-27T08:01:02Z
Temporal Coverage End 2020-03-11T07:47:06Z