Aza-crown-stabilized Alkali-Alkalide Systems: Solvent and metal effects on diffusion and methyl group dynamics

DOI

We request 4 days on IRIS to investigate the diffusional and rotational dynamics of the alkalide forming, fully methylated aza-crown hexamethyl-hexacyclen (HMHC) in solution.Through partial deuteration of HMHC we can isolate these motions, and thus determine the effect of alkalide binding and solvent in two systems (dimethyl ether, isopropylamine).

Identifier
DOI https://doi.org/10.5286/ISIS.E.63526428
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/63526428
Provenance
Creator Dr René Riedel; Dr Andrew Seel; Professor Peter Edwards; Professor Anthony Barrett; Dr Victoria Garcia Sakai
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-09-18T08:00:00Z
Temporal Coverage End 2015-09-23T07:00:00Z