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HD dynamics in ice XVII
The proposing team has recently obtained important neutron scattering results on samples of different kind of ice containing molecular hydrogen (sII and sH hydrogen-filled... -
Hydrogen phase behaviour in microporous carbons with different pore geometries
In this proposal, we seek to use quasielastic neutron scattering (QENS) to investigate the phase behaviour of molecular or di-hydrogen (H2) in cylindrical and slit-shaped pores... -
INS Study of Nb2O5-supported Pt, Pd and Ru catalysts for the Efficient Lignin...
We request 9 days on TOSCA to carry out INS study of the hydrogenolysis of 4-methylphenol on Pt, Pd and Ru-loaded Nb2O5 catalysts for lignin conversion. This proposed study will... -
Determination of the structure of methoxy on eta-alumina
We have recently demonstrated that we are able to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this is a... -
Uptake of Molecular Hydrogen by High-performance Carbon Nanostructures (NIMROD)
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
Stochastic vs. Intermolecular Motions in Strongly Associated Liquids: The Cas...
Neutron scattering is a powerful technique to study stochastic motions in liquids but it requires an energy resolution well below the meV range. As a consequence, quasielastic... -
Diffraction investigation of cyclic molecules on surfaces of different symmetry
The wetting of solid surfaces by gases and liquids is both fundamentally and technologically important especially in the areas of energy storage and conversion, e.g. catalysis.... -
Mechanism of hydrogen residue in metal hydrides formed from high-entropy allo...
High-entropy alloys (HEAs) typically contain four or more principle elements in equimolar amounts. We have recently discovered the first bcc HEA-based hydride with reversible... -
QENS Investigation of Solid Ammonia
A recent beautifully resolved INS spectrum of solid ammonia shows distinct differences in phonon states compared to initial calculation. This suggests that strong... -
Diffusional Dynamics of Molecular Hydrogen Bound to Carbon Nanohorns
The present experiment aims to elucidate the energetics and geometry of translational diffusive motions exhibited by molecular hydrogen bound to carbon nanohorns. Previous... -
QENS studies of Na-ion battery materials
LixCoO2 is used extensively in portable batteries in laptops and mobile phones, but the scarcity of Li means that alternative materials are required. Structurally related... -
Understanding the mechanism of benzyl alcohol oxidation using supported Au-Pd...
This proposal is a continuation of RB1000003. The aim of the present experiment is to gain further insight into the mechanism of benzyl alcohol oxidation using supported Au-Pd... -
In Situ Inelastic Neutron Scattering Studies of Gas-Loaded Porous Framework S...
We request 12 days on TOSCA to study the interaction of adsorbed N2, CO2, CH4 and NO with a hydroxyl-decorated aluminium-based MOF NOTT-300. This proposed study will investigate... -
Commissioning of the Sputnik pressure cell at low temperatures
making it available to users in the future -
Hydrogen dynamics in clay nanotubes
We will study H2 dynamics in the nanotubular clay imogolite whose structure has an external diameter of ~2.5 nm and an inner diameter of <1 nm. The tube length of synthetic... -
Structure of Molecular Hydrogen in Synthetic Laponite Clay Hydrates
In this proposal we aim to study low temperature structure of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual motivations for this... -
QENS studies of molecular hydrogen in K-doped electrospun graphite nanofibres
The physisorptive capability of graphite-based nanomaterials for hydrogen is strongly dependent on their surface areas and nanomorphologies. We have made electrospun graphite... -
INS investigation of the effects of hydration on the dynamics of natural silk...
Silk materials have been the focus of renewed attention because they exhibit extraordinary mechanical strength and toughness.Two main factors are critical for understanding... -
In situ Investigation of the Locations of Gas Molecules within a Decorated Po...
We request 4 days on WISH to study the preferred binding sites and locations of adsorbed gas molecules (CO2,NO2 and D2) within a decorated Al(III)-carboxylate porous framework... -
Zr-based metal-organic frameworks as carbon-free energy carriers: a study of ...
Combined with computational modeling, in situ inelastic neutron scattering (INS) will be employed to reveal the nature of the interactions between stored ammonia and the host...