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PROBING DRUG PHARMACODYNAMICS BY INS - THE EFFECT OF CISPLATIN-LIKE ANTICANCE...
Cancer is a growing health problem worldwide, and thus the development of effective chemotherapeutic approaches is crucial for improving human health. Much effort has been put... -
Hydrogen phase behaviour in microporous carbons with different pore geometries
In this proposal, we seek to use quasielastic neutron scattering (QENS) to investigate the phase behaviour of molecular or di-hydrogen (H2) in cylindrical and slit-shaped pores... -
Determination of the structure of methoxy on eta-alumina
We have recently demonstrated that we are able to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this is a... -
The application of INS to investigate the methanol-to-gasoline reaction over ...
We propose to use MERLIN to measure INS from commercial zeolite catalyst samples extracted from a reactor in which they have been exposed to dimethylether for different lengths... -
Structural characterisation of chemisorbed methoxy in ZSM5: an intermediate i...
Zeolites and zeotype materials are well established in the field of catalytic science. Particularly notable is their use for shape selective, acid-catalyzed conversions of... -
Study of the S(Q, w) map of propane/propene adsorbed on non-charged ITQ-29 Ze...
Zeolites are perhaps the most successful microporous materials used for catalysis and separation processes in refineries and chemical industries[1-3]. This is due to the... -
Determination of the diffusion of propane/propene mixtures adsorbed on non-ch...
Zeolites are perhaps the most successful microporous materials used for catalysis and separation processes in refineries and chemical industries[1-3]. This is due to the... -
The mechanism of CO oxidation over PdO.H2O
The aim of the present proposal is to investigate the mechanism of CO oxidation over hydrous palladium oxide, both directly and indirectly. For the direct route, the sample will... -
Probing the interaction of hydrogen with supported gold nanoparticles
Small gold nanoparticles (1-5 nm) supported on metal oxides are extremely active catalysts for C-C coupling, aerobic oxidations and selective hydrogenations. The interaction of... -
The use of INS to evaluate evolutionary processes associated with bringing ir...
In collaboration with a major provider of Fischer-Tröpsch synthesis (FTS) catalytic technology, the research team have recently demonstrated how INS can be used to probe iron... -
INS studies of the interaction of propene with ZSM-5
Fluidised Catalytic Cracking (FCC) units are one of the major conversion units in modern petrochemical refineries. ZSM-5 additives are used in FCC units to convert gasoline... -
Characterisation of intermediates in CO oxidation over Pd/Al2O3.
Recent infrared measurements by one of the applicants (GR) have shown that CO and CO2 adsorption on alumina-supported palladium catalysts form a variety of carbonate species. In... -
Investigation of the Interactions Between Porous Frameworks and Adsorbed Gas ...
We request a total of 9 days on TOSCA:6 days to investigate the interactions exhibited by two Li containing metal-organic framework materials on loading with CO2. Doping of Li... -
Characterisation of intermediates in the production of eta-caprolactam
The commercially important polymer Nylon 6 is manufactured by ring-opening polymerization of eta-caprolactam. Industrially, eta-caprolactam is made by the Beckmann rearrangement... -
Catalytic Hydrodeoxygenation of Benzyl Phenyl Ether as a Lignin Model Compound
Bio-oil is a renewable energy from biomass, however, its high content of oxygenates result in low heating values and chemical/thermal instability. One effective upgrading... -
Probing of hydride phase formation of Pd nanoclusters embedded in the NH2-UiO...
With this proposal, we would like to investigate a material that could be used as a catalyst for hydrogenation reactions. A catalyst acts to increase the rate of a reaction by... -
Morphology-activity relationships in catalysis promoted by MoOx nanoparticles
Metal and metal oxide nanostructures can be prepared in much different morphology (nanowires, nanobelts, nanofibres etc.) which are known to exhibit better adjustable properties... -
The chemisorption of hydrogen over a Raney cobalt catalyst: An INS investigation
Building on a successful programme investigating aspects of iron based Fischer-Tropsch synthesis (FTS) catalysts, it is opportune to extend that work to include Co FTS... -
Investigation into the reversibility of TiCl4 doped NaALH4
Hydrogen Storage still remains the technology bottleneck for a more widespread use of hydrogen. Solid complex hydrides such as amides, alanates and borohydrides have been... -
Analysing intermediates of a CO2 insertion reaction using simultaneous operan...
Atmospheric levels of CO2 are increasing at uncontrolled levels and as such methods of CO2 utilisation are being researched. A key reaction for this purpose is the coupling of...