-
The interpenetration of two poly(ethylene oxide) polymer brushes under confin...
Coating two surfaces with polymer brushes has been shown on many occasions to reduce friction by orders of magnitude. These ultra-low frictions are believed to stem from be the... -
Elucidating buried structures using Offspec
This proposal is a continuation proposal (previous RB 1110285) utilising the Offspec instrument and is aimed at further understanding the utility of the spin echo grazing... -
A Model for Tackifier Elastomer Interaction
Oligomers are commonly added to adhesives in order to improve surface tack properties. However, it is also important that the oligomers do not adversely affect the solid (glassy... -
Chain Conformations in Monodisperse/Polydiserpse Electrospinning Solutions
Electrospinning is a technique which produces fibres from a polymer solution exposed to an electric field. The technique forms fibres substantially smaller in diameter than a... -
Basic Science for Offpsec : Part 2
This proposal is part 2 of a set of two proposals on Offspec aimed at understanding some of the effects seen in off-specular data and in particular the use of the spin echo... -
Impact of Elasticity on Surface Wetting
We have recently characterised a surface wetting transition for a low molecular weight oligomer in a high molecular weight rubbery polymer. Although weak surface segregation of... -
Ionic Liquid Aggregation in Polymers
Ionic liquid/Polymer mixtures, where the ionic liquid is the minority component are of particular interest for their potential as high temperature plasticisers and conducting... -
Can surfactants be pushed out of polymer layers by applying compression?
For many applications such as paints, foods and drug formulations, aggregation of colloidal particles is prevented by combining polymer and surfactant adsorption. Key to this... -
Multiscale time-resolving study of crystallisation in polyethyleneoxide
We will exploit the powerful and unique capability of NIMROD to follow in a time-resolving manner the crystallisation of polyethyleneoxide (PEO). There are three key length... -
A Model for Tackifier Elastomer Interaction
Oligomers are commonly added to adhesives in order to improve surface tack properties. However, it is also important that the oligomers do not adversely affect the solid (glassy... -
Surface modification in heteropolymer blends.
In recent years we have had considerable success with the surface modification of amorphous and crystalline thermal plastic polymers using multi-end functional additives. In... -
Local structure of polymers in confined geometries in surface dominated samples
This proposal is focused on developing an understanding of how surfaces affect the local structure of synthetic polymers. There is considerable evidence for a strong variation... -
SANS studies of electrospun polystyrene-ammonia borane nanostructures
Increasing the density of hydrogen storage under ambient conditions is a critical requirement for the widespread introduction of low-carbon hydrogen vehicles. Ammonia borane... -
Structure of Confined Albumin Layers
In the context of a project in collaboration with ISIS that focuses on structural studies under mechanical confinement, with a specific focus on biological lubricants, the... -
Testing the efficacy of the spin echo technique combined with the dynamical t...
The sensitivity of the Spin Echo Resolved Grazing Incidence Scattering (SERGIS) to scattering geometry and sample specifications has been tested at OFFSPEC on gratings with... -
Surface structure of monolayers formed by novel di- and tri-chain cationic li...
The aim of the present study is to the determine, using specular neutron reflection (SNR), the structure of layers formed by novel tri-chain cationic lipids in combination with...