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Quasi-elastic neutron studies of superstructure formation in battery materials
LixCoO2 is used extensively in portable batteries in laptops and mobile phones, but the scarcity of Li means that alternative materials are required. Structurally related... -
Divacancy superstructures and enhanced thermopower in NaxCayCoO2
Replacing Na ions in NaxCoO2 with divalent Ca ions results in the formation of ordered arrays of divacancy clusters, rather than the trivacancy clusters found for the pure... -
Structural distortions and magnetic ordering in oxygen depleted spin ice
Geometrical frustration in the spin ice material Dy2Ti2O7 leads to macroscopic degeneracy and the observation of magnetic diffuse neutron scattering down to the lowest... -
Defects and spin correlations in yttrium-doped spin ice
Excitations in spin ice fractionalize into de-confined magnetic monopoles that interact with each other via the magnetic Coulomb interaction. Substituting rare earth ions with... -
Magnetic structure of beta-MnRu
We have recently succeeded in isolating single crystals of Beta-MnRu, which we know propose to study using the WISH diffractometer. Previous powder measurements of beta-MnRu... -
High temperature superstructures in thermoelectric oxides
Sodium cobalate has emerged as one of the best thermoelectric materials. Our previous neutron Laue diffraction studies on SXD have found ordered arrays of multivacancy clusters,... -
The effect of sodium ordering on rattling modes in sodium cobaltate
NaxCoO2 has exceptional thermoelectric properties, including low thermal conductivity, and it is currently under consideration for use in power recovery applications and as a... -
Influence of superstructures on rich transport properties of lithium cobaltate
In the vicinity of x ~ 0.75, LixCoO2 has potential as a thermoelectric, since it has a high Seebeck coefficient and metallic conductivity. We have performed the first successful... -
The effect of magnetic structure on ordred/disordered IrMn3 exchange-biasing ...
The exchange biasing effect in the thin film IrMn3/Fe depends strongly on the degree of structural ordering of the underling antiferromagnetic IrMn3 pinning layer. In this work... -
QENS studies of Na-ion battery materials
LixCoO2 is used extensively in portable batteries in laptops and mobile phones, but the scarcity of Li means that alternative materials are required. Structurally related... -
Structural Phase Diagram of the new Multiferroic Hexagonal YbFeO3
This experiment aims to map out the structural phase diagram of the new multiferroic compound hexagonal-YbFeO3 as a function of temperature, both above and below room... -
Subtle magnetic phase transitions in multiferroic BiFeO3
This experiment seeks to probe the magnetic structure of multiferroic BiFeO3 and its evolution on lowering temperature, with the specific aim of identifying magneto-structural... -
Electronically-driven structural transition in Ti-doped Ca3Ru2O7
The purpose of the experiment is to determine the effect of titanium doping on the structural and magnetic transitions of Ca3Ru2O7. The pure material undergoes a Néel transition... -
Understanding enhanced thermoelectric properties of sodium cobaltate doped by...
The thermoelectric power factor for (Na1-y¿My¿)0.8CoO2 is dramatically increased when M = Sr, but it is essentally unchanged from the pure compound when M = Ca. Our previous SXD... -
The high temperature phases of multiferroic YMnO3
Hexagonal YMnO3 is a well-studied, but poorly understood, multiferroic material, which adopts the 'geometric' mechanism of ferroelectric distortion, rather than the more normal... -
Rattling modes in new thermoelectrics
NaxCoO2 has an exceptional combination of thermoelectric properties, including low thermal conductivity, and it is currently under consideration for use in power recovery and as... -
Superstructures in lithium cobaltate
The battery material LixCoO2 has recently been shown to have high thermopower comparable to NaxCoO2 at high x. In the case of NaxCoO2 we showed using neutron Laue diffraction on... -
Superstructures in insulating and metallic lanthanum-doped sodium cobaltate
The thermoelectric properties of NaxCoO2 can be substantially improved by replacing Na ions by cations of higher valence. Our neutron diffraction studies on SXD for doping with... -
The elusive ¿cubic¿ phase of BiFeO3 and related materials
We wish to probe the suggested existence of a high-temperature cubic perovskite phase in the multiferroic material BiFe0.7Mn0.3O3. The parent phase of this material, BiFeO3, was... -
The Definitive Sodium Niobate Phase Diagram?
NaNbO3 has long been regarded as the 'most complex' perovskite known, with at least seven different phases reported as a function of T, at least two of which have evaded all...