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Bi0.775Ln0.225O1.5 (Ln = La, Dy) Oxide Ion Conductors: Local Structure, Compl...
Ionic conductivity is a property where a material is able to conduct electricity through the movement of ions. Oxide ion conductors can be used in solid oxide fuel cells, which... -
Ordering in La/W Double Substituted Bismuth Oxide Based Fluorites
Materials that show fast oxide ion conduction have potential applications as electrolytes in devices such as solid oxide fuel cells (SOFCs), gas sensors and gas separation... -
A variable temperature study of polymorphism in Li2+2xM1-xSiO4 electrode mate...
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap andsafe cathodes. Recently, silicate-based cathodes have been described,... -
The elusive ¿cubic¿ phase of BiFeO3 and related materials
We wish to probe the suggested existence of a high-temperature cubic perovskite phase in the multiferroic material BiFe0.7Mn0.3O3. The parent phase of this material, BiFeO3, was... -
Mass-selective Neutron Spectroscopy of Molten FLiBe
We request time on VESUVIO to study the properties of FLiBe using mass-resolved neutron spectroscopy (MANSE). FLiBe is a mixture of BeF2 and LiF and its physical properties in... -
Texture measurement and in-situ annealing of hot-rolled α + β dual-...
The experiment will use neutron diffraction to analyse a hot-rolled matrix of dual-phase ZrNb alloys, in order to measure the macroscopic texture dependence on temperature,... -
In-situ Formation of Fast Lithium Conducting garnets via low temperature sol-...
Increasing global population, global warming and depletion of fossil fuels have resulted in a growing need for better energy storage. Lithium-ion batteries are promising devices... -
In-situ Variable Temperature Studies of Dy Doped BiFeO3
Multiferroics and in particular BiFeO3 have recieved alot of interest. The potential of multiferroic materials to be incorporated into many devices such as sensors and memory... -
Local Structure in Ni-Cr Solid Solutions
The future of aviation relies on the improvement of the efficiency of the jet-turbine engines, which is in turn reliant on the properties of the materials (specifically the... -
In-situ Neutron Diffraction Study of Proton Conducting Perovskite Oxide BaZr0...
Acceptor-doped perovskite oxides exhibit significant proton conductivity under humid or hydrogen containing atmosphere, which opens a unique possibility to be used as... -
Investigating the presence of an order-disorder transition in La6Y4Ge6O27
Apatite-type phases have been attracting interest as a new class of oxide ion conductors, and in these systems, the key defects are oxide ion interstitials. We have recently... -
Determination of lithium ion diffusivity in the lithium-ion cell cathode mate...
With the decreasing cost of energy generation by renewable sources, energy storage is becoming increasingly critical to energy security across the globe. Lithium iron phosphate... -
Phase Transitions in Pb/Y di-substituted Bi2O3 Based Electrolytes
There has been recent interest in the use of cermets based on stabilised delta bismuth oxide based solid electrolytes as cathodes in solid oxide fuel cells. It has been shown... -
Defect Structure in Lead Doped Bismuth Yttrates
Stabilised bismuth oxides are of interest as intermediate temperature solid electrolytes for a variety of electrochemical device applications. Lead doping into bismuth yttrate... -
Programme Access Rosseinsky
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In-situ study of structure-property relationships on proton conducting perovs...
Significant research has been given towards synthesis and characterisation of electrolyte materials with high proton conductivity for intermediate temperature range (200-600°C)... -
Glasses and supercooled liquids in the Se-Cl system
Little is known on the structure and properties of vitreous Se doped with halogens in contrast to group III, IV, V, and VI dopants and also many metal additives. Our Raman... -
High-Temperature Crystal Structure of Aluminium-Substituted La(Sr)Ga(Mg)O3-d ...
Due to a high-oxide ion conductivity, strontium and magnesium co-substituted lanthanum gallate (LSGM) is considered as a potential electrolyte material for solid oxide fuel... -
Apatite-type Oxides for Energy Applications: Role of Lattice Dynamics
Lanthanum-containing germanate apatites are materials with potential applications as electrolytes in solid oxide fuel cells. The conductivity of these materials is known to... -
In-Situ Studies of Electrochemically Enhanced Performance in Perovskite Elect...
Recent studies in our laboratory have shown that a range of A-site deficient perovskite oxides, with carefully tuned chemical compositions, exhibit excellent properties when...
