In-situ neutron study of Oxygen absorption in YBaCo4O7+δ

DOI

A recent addition to the list of emergent materials is the ReBaCo4O7+delta family of compounds. Indeed, due to the magnitude of their oxygen uptake and release capability, they are very promising materials for applications ranging from solid-oxide fuel cells to gas-separation membranes and oxygen sensors. Whilst there is no doubt that YBaCo4O7+delta can accommodate oxygen up to delta= 1.5, the mechanisms behind this huge uptake is unclear. Although there has been some success in stabilizing structures with high delta values, in-situ studies are clearly needed to understand the process. So far, these in-situ studies have only been performed with X-rays and the amount of information obtained on the oxygen has intrinsically been limited. We therefore propose to perform in-situ neutron diffraction study of the oxygen absorption in YBaCo4O7+delta.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24088877
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24088877
Provenance
Creator Dr Pascal Manuel; Dr Laurent Chapon; Dr Dmitry Khalyavin; Dr John Mitchell
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-06-06T18:48:51Z
Temporal Coverage End 2012-06-11T20:32:26Z