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Structure of ethylammonium nitrate-water mixtures
We propose to explore the morphology of Ethylammonium Nitrate (EAN, a protic ionic liquid, PIL)-water mixtures. Both components are polar, protic compounds whose structure is... -
Formulating polymer solutions to stabilise polymeric foams
Polyurethane foams (PUFs) are commonly prepared by mixing Pluronic type copolymers and isocyanate reactive monomers in the presence of additives e.g. catalysts, blowing agent... -
In-situ study of hydrogen absorption and desorption in metal-hydride hydrogen...
In order to develop our understanding of hydrogen coordination as a function of pressure within two titanium-chromium-vanadium-molybdenum alloys, Ti10Cr10V75Mo5 and... -
Spontaneous surface multilayer formation in oligoamine ¿ surfactant mixtures
This proposal is part of a major EPSRC (EP/GR065705)/Unilever funded programme to develop and control the spontaneous formation of surfactant multilayer structures at... -
Swelling of Single Supported Bilayers ¿ First Systematic Investigation of the...
This proposal addresses bilayer swelling experiements on floating supported bilayers (FSBs) in the presence of biological buffers. Previous work on multilamellar vesicles has... -
pH Responsive Polymer Blend Surfaces
Polymers, end-functionalised with carboxylic acid (COOH) groups do not normally segregate to film surfaces due to the high surface energy of these functionalities. However, we... -
Polyoxometallate surfactant adsorption at solution surfaces
Polyoxometallates (POM) are well defined transition metal clusters with a range of interesting catalytic, magnetic and optical properties. To make efficient use of these... -
Oxidation of thin film at the air-water interface of cloud droplets using REA...
The Earth's climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects droplet size and optical properties, important effects. Common... -
pH-Responsive Polyelectrolyte Brushes Studied by Neutron Reflectivity and in ...
pH-responsive polymer brushes comprise of long polymer chains of either a weak acid or base chemically attached to a surface. Depending upon the degree of ionisation along the... -
Improved lignin conversion via selective cleavage of interunit C-C bonds to m...
We request 9 days on TOSCA to carry out inelastic neutron scattering (INS) studies of the adsorption, activation and reaction of polycyclic aromatic hydrocarbons (lignin models)... -
Hydration and chain entanglement in random poly(HEMA-co-PEG10MA) brushes
Marine biofouling compromises function and reliability of marine equipment, causing considerable economic and environmental damage. Biocides for fouling prevention are... -
Adsorption Kinetics and Structure of Silicatein Mediated Silica Films
The fabrication of composite coatings based on silica with well defined physical properties represents a promising new approach to fine-tune mechanical, optical, electronic, and... -
Disorder in substituted beta-tricalcium phosphate for waste immobilisation
We have a long established interest in the materials used for the immobilisation of nuclear waste from the domestic power industry and legacy waste from various defence... -
Elucidating molecular mechanism of membrane disruption by designed α-hel...
We have previously shown that peptides such as G(IIKK)4I-NH2 (G4) can kill bacteria and inhibit cancer cell growth whilst remaining benign to mammalian host cells. We have also... -
Multilayering of Methyl Ester Sulphonates at the Air-Aqueous Interface: Effec...
Surfactants usually form a single layer of molecules at the surface of water. We have shown that under certain conditions more than one layer may form. When this happens the... -
The Effect of the Head Group on Multilayering of Alkanoic Alkyl Ester Sulphon...
We have shown that under certain conditions multilayer adsorption of surfactants occurs at the air-water interface. in which case the system becomes a powerful wetting agent (it... -
Probing membrane localisation of molecular rotors (NR)
A number of important biological processes, such as intracellular transport and signal transduction depend on the viscosity and the distribution of microdomains in cells. We... -
Surfactant mixing at hydrophilic solid/aqueous interfaces
By applying the regular solution model (RS) to the determination of composition in a mixed surfactant layer adsorbed at a hydrophilic solid/aqueous interfaceand combining it... -
Cationic surfactants adsorbed to titanium dioxide-effect of pH and added elec...
Titanium dioxide (TiO2) is used in a wide range of applications from medical and dental implants to treatment of contaminated air and water streams. However many of the... -
Effect of Temperature on the Transbilayer Structure of a Model Erythrocyre Me...
In recent years, it has become understood that rather than being homogenous mixtures, biomembranes show a complex phase behaviour, with regions of uniform phases, and others...