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Metastable Water Ice and Nitric Acid ¿ observing the phase changes
The IPCC report 2007 underlines the particular importance of aerosol particles for the water cycle and the radiation balance, and thus for the global climate. In Cirrus clouds... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
Characterisation of Pearlman's catalyst
Pearlman¿s catalyst is commonly used in various hydrogenation, arylation and O-debenzyaltion reactions. The catalyst is unusual that it is active but not pyrophoric. It is... -
IINS measurements on the terminating protons of the basic structural units of...
More than 6 million tonnes of carbon black per year are produced worldwide. The major part is used as reinforcing filler material in tyres and mechanical rubber goods. For... -
Continuation: Metastable Water Ice and Nitric Acid ¿ observing the phase changes
Nitric acid plays important roles in the atmosphere, in all aggregate states and combined with water.During the last periode we were running the proposal RB1110207 "Metastable... -
Characterisation of on-top hydrogen on fuel cell catalysts.
A key step in a fuel cell is the dissociation of hydrogen gas to provide protons and electrons by a catalyst. For low temperature fuel cells carbon black supported... -
Characterisation of tunnelling modes of adsorbed methoxy on eta-alumina
Our previous proposal strongly suggested that the methyl groups of adsorbed methoxy on eta-alumina do exhibit tunnelling. This application aims to provide additional evidence to... -
Does the methyl group of adsorbed methoxy on eta-alumina tunnel?
This application seeks to discover whether it is possible to observe the tunnelling of the methyl groups of adsorbed methoxy on eta-alumina. To our knowledge, this is the first... -
Structures and magnetism of layered cobalt oxide selenide tellurides
This proposal aims to exploit the high resolution of HRPD and OSIRIS to probe the structures of the solid solution Ba2CoO2Cu2(Te1-xSex)2. The compound Ba2CoO2Cu2Te2 shows... -
Investigation of the ligand interaction in thiol-capped Au and Pd nanoparticl...
Organic stabilisers, such as thiols, thioethers, amines and polymers (i.e. polyvinylalcohol) have been used for the stabilisation of metal nanoparticles. The catalytic... -
The application of INS to examine high specification Fe Fischer-Tropsch catal...
Over the last 4-5 years the research team have been developing INS methodology that can be applied to investigate Fe Fischer-Tropsch (F-T) catalysts. The first stage of that... -
An investigation into the structure of zeolites ZSM-5, Beta and Y as a functi...
The inelastic neutron scattering spectrum of commercial samples of industrially important zeolites ZSM-5 (Si/Al ratios: 25, 30, 80,and 280), Beta (Si/Al ratios: 25, 38, and 300)... -
Quantification of hydrocarbonaceous overlayers relevant to the induction of i...
Recent experiences applying INS to examine a series of nickel-based methane reforming catalysts have enabled a generic experimental methodology to be developed. In collaboration... -
Correlation of structures, compositions and magnetism of copper-deficient lay...
This experiment will investigate three related systems which contain copper deficient anti-fluorite-type copper sulfide layers. The overall aim is to correlate magnetic and... -
Probing the nature of the interactions at the surface of fuel cell catalysts ...
The objective of this proposal is to identify the nature of species formed on the surface of the catalyst material when they are exposed to typical fuel cell feed stocks and... -
An INS Study of the Effect of Pressure on the Crystal Structure Titanium Tetr...
TiCl4 forms a molecular structure containing isolated tetrahedral molecules on cooling to 248 K. The freezing pressure of TiCl4 is 0.05 GPa (500 atm). Single crystal growth... -
INS study of the effect of particle size on the formation of beta-palladium h...
Finely divided, supported palladium particles are used as catalysts in many technical processes. However, there is still considerable potential to improve catalyst performance... -
The expoitation of the A, B, C spectral signatures of H-bonds.
Intermediate strength hydrogen bonds, H-bonds, are known to play a role in the reactions of surface bound species, especially on the widely used industrial substrate... -
Exploring Polymer Vibrations under Extreme Confinement: Substrate Effects
We seek to explore extreme confinement on the vibrational density of states of polyethylene oxide (PEO) over a wide energy-transfer range (10-3000 cm-1). These experiments are... -
INS Determination of the Surface Properties of Nanoparticle Pollutants
Metal oxide nanoparticles are a form of pollution generated by a number of industrial procedures, and there is evidence that this class of nanoparticle can have a detrimental...