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Search for magnetic resonance in the superconducting state of Mo3Sb7
The intermetallic Mo3Sb7 compound exhibits superconductivity at Tc=2 K and exhibits interesting physical properties in the magnetic susceptibility, electrical resistivity and... -
Copy of: Solvation dynamics of the phosopholipid 1,2-dipropanoyl-sn-glycero-3...
It is well known that water is the medium in which the overwhelming majority of biological processes take place. In cell membranes water molecules are thought to be essential to... -
Melting point dynamics of Confined fluids
This proposal aims to investigate the dynamics of the melting transition in H2O and CO2 when confined in a vycor (SiO2) matrix. The field of fluids in confined geometries is... -
Total scattering study of the II to I phase transition in pyridine
Atomistic characterisation of phase transitions in organic materials is important because of the role played by polymorphism in pharmaceuticals and agochemicals. Conventional... -
QENS Investigation of Solid Ammonia
A recent beautifully resolved INS spectrum of solid ammonia shows distinct differences in phonon states compared to initial calculation. This suggests that strong... -
Phase Transitions and Orbital Ordering in SrRu1-xCuxO3.
This proposal seeks to establish the importance of orbital ordering on the stability of the tetragonal phase in Cu doped SrRiuO3. Orbital ordering is believed to be a... -
Is Zeolite Deactivation Through Pore Blocking?
Zeolites are porous framework materials that have active catalytic sites inside narrow channels. Unwanted reactions create coke in the pores which may block access to the active... -
Thermodynamics of Non-Uniform Compression in H-Bonded Molecular Solids
Equations of state (EoSs) show how the thermodynamic variables of temperature, pressure and volume are inter-related. The ideal gas law, PV = nRT, is an example of an EoS which... -
Order and disorder in (Mn,Fe)2(P,Si) magnetocaloric compounds
In the high-performance and low-cost (Mn,Fe)2(P,Si) magnetocaloric compounds, the detrimental hysteresis has been significantly reduced by balancing Mn:Fe and P:Si ratios, which... -
Local structure of the ferroelectric and giant barocaloric (ND4)2SO4
Ammonium sulfate has a well-known order-disorder phase transition at -50 ºC: initially of interest for the ferroelectric behaviour in the low-temperature phase, this has... -
The effect of sodium ordering on rattling modes in sodium cobaltate
NaxCoO2 has exceptional thermoelectric properties, including low thermal conductivity, and it is currently under consideration for use in power recovery applications and as a... -
Reorientational dynamics in a low-dimensional glass
Most of the features exhibited by canonical glass-formers can also be found in systems with a high-degree of translational order. In addition to the well-known orientationally... -
Thermal expansion and ordering in D2O ice III / IX
The high-pressure form of solid water, ice III, is the equilibrium phase in contact with liquid water at pressures from about 2.0 - 3.5 kbar. Consequently, its properties are... -
Structural phase diagram of hydrated silks
The formation of silk fibres in both spiders and silkworms is characterized by a conversion of short range ordered structures in solution into long range ordered beta-sheet rich... -
Probing nanophase segregation in aqueous solutions
In recent experiments we accidentally observed the onset of nanophase segregation in concentrated LiCl-water solutions by increasing dilution, in the deeply undercooled regime.... -
Alkali metal anions in solution Ion pairing and aggregation as a survival s...
Alkali metals are soluble in organic media when a macrocyclic complexing agent is used in order to drive the dissolution process by formation of complexed metal cations and... -
Characterising new high-pressure phases of ammonia monohydrate
Over the past two years I have carried out high-pressure surveys of the ammonia monohydrate (AMH) phase diagram using a Paris-Edinburgh press mounted on the D20 beam-line at the... -
Dynamics of Water on Surface of Reverse Osmotic Membranes
We are proposing 10 days of beamtime on IRIS to investigate the diffusion process of H2O molecules adsorbed on polyamide, surface material of reverse osmotic membranes currently... -
Study of pore-confined CO2 depletion below the bulk triple point
Freezing of fluids confined at the nanoscale is of great importance for the understanding of their behaviour due to the confinement effects arising from the finite pore size and... -
Water diffusion mechanism in hydrated amorphous calcium carbonate
Calcium carbonates are highly important in geochemistry and especially in biomineralization. In nature, organisms can form each of the anhydrous polymorphs selectively for...
